Ethyl 2-methylhydrazinecarboxylate

Base Information

• Chemical Name: Ethyl 2-methylhydrazinecarboxylate
• CAS No.: 25726-31-2
• Molecular Formula: C4H10N2O2
• Molecular Weight: 118.136
• DSSTox Substance ID: DTXSID80494963
• Wikidata: Q82342754
• Mol file: 25726-31-2.mol

Synonyms:25726-31-2;ethyl 2-methylhydrazinecarboxylate;SCHEMBL4044207;N-carbethoxy-N'-methylhydrazine;SCHEMBL22990401;DTXSID80494963;Ethyl 2-methylhydrazine-1-carboxylate;AKOS040766756

Chemical Property of Ethyl 2-methylhydrazinecarboxylate

Chemical Property:

• XLogP3: 0.1
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 3
• Exact Mass: 118.074227566
• Heavy Atom Count: 8
• Complexity: 74.4

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCOC(=O)NNC

Technology Process of Ethyl 2-methylhydrazinecarboxylate

There total 1 articles about Ethyl 2-methylhydrazinecarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

methylhydrazine (60-34-4) + Diethyl carbonate (105-58-8,76619-83-5) → ethyl 2-methylcarbazate (760-81-6) + 2-methyl-1-ethoxy-carbonyl-hydrazine (25726-31-2)

Guidance literature:

In diethyl ether; for 46h; Heating;

DOI:10.1055/s-2004-820020

Reference yield:

2-methyl-1-ethoxy-carbonyl-hydrazine (25726-31-2) + 4-chloro-2-fluoro-phenyl isothiocyanate (68034-69-5) → 4-(4-chloro-2-fluoro-phenyl)-2-methyl-1-ethoxycarbonyl-thiosemicarbazide

Guidance literature:

With sodium hydrogencarbonate; In water; acetonitrile;

Reference yield:

2-methyl-1-ethoxy-carbonyl-hydrazine (25726-31-2) + phenyl isocyanate (103-71-9) → 1-Ethoxycarbonyl-2-methyl-4-phenylsemicarbazid (34771-21-6)

Guidance literature:

In benzene;

DOI:10.1002/ardp.19713040912

upstream raw materials:

methylhydrazine

Diethyl carbonate

Downstream raw materials:

3-3-methyl-ethyl-carbazat

1-Ethoxycarbonyl-2-methyl-4-phenylsemicarbazid

3--3-methyl-ethyl-carbazat