4-Methoxybenzenesulfinothioic acid S-phenyl ester

Base Information

• Chemical Name: 4-Methoxybenzenesulfinothioic acid S-phenyl ester
• CAS No.: 26974-29-8
• Molecular Formula: C₁₃H₁₂O₂S₂
• Molecular Weight: 264.369
• Mol file: 26974-29-8.mol

Synonyms:Benzenesulfinothioic acid,4-methoxy-,S-phenyl ester;4-Methoxy-benzolthiosulfinsaeure-S-phenylester;4-methoxy-benzenethiosulfinic acid S-phenyl ester;Benzenesulfinic acid,p-methoxythio-,S-phenyl ester;

Chemical Property of 4-Methoxybenzenesulfinothioic acid S-phenyl ester

Chemical Property:

• Boiling Point: 440.0±47.0 °C(Predicted)
• PSA: 70.81000
• Density: 1.34±0.1 g/cm3(Predicted)
• LogP: 4.37580

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4-Methoxybenzenesulfinothioic acid S-phenyl ester

There total 2 articles about 4-Methoxybenzenesulfinothioic acid S-phenyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-(4-methoxyphenyl)-2-phenyldisulfane (95914-29-7) → S-(4-methoxyphenyl) benzenethiosulfinate (26974-26-5,133670-28-7,133751-12-9) + S-phenyl 4-methoxybenzenesulfinothioate (26974-29-8,133670-29-8,133751-13-0)

Guidance literature:

With 3H-2,1-benzoxaselenole Se-oxide; dihydrogen peroxide; In methanol; dichloromethane; at 20 ℃; for 3h; Overall yield = 43 %;

DOI:10.3390/molecules200610748

Reference yield:

p-methoxybenzenesulfinyl chloride (31401-23-7) + thiophenol (108-98-5) → S-phenyl 4-methoxybenzenesulfinothioate (26974-29-8,133670-29-8,133751-13-0)

Guidance literature:

With pyridine;

upstream raw materials:

p-methoxybenzenesulfinyl chloride

thiophenol

1-(4-methoxyphenyl)-2-phenyldisulfane