Technology Process of Benzenecarbodithioic acid, 4-methoxy-, propyl ester
There total 4 articles about Benzenecarbodithioic acid, 4-methoxy-, propyl ester which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
propyl 1H-imidazole-1-carbodithioate;
With
1,10-Phenanthroline; nickel(II) bis(acetylacetonate) hydrate;
In
tetrahydrofuran; 1,4-dioxane;
at 23 ℃;
for 0.166667h;
Inert atmosphere;
Sealed tube;
4-methoxyphenylzinc chloride;
In
tetrahydrofuran; 1,4-dioxane;
at 23 ℃;
for 1h;
Inert atmosphere;
Sealed tube;
DOI:10.1021/acs.orglett.1c04074
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: magnesium; lithium chloride / tetrahydrofuran; ethylene dibromide / 2 h / 20 °C / Inert atmosphere; Sealed tube
1.2: 1 h / 20 °C / Inert atmosphere; Sealed tube
2.1: nickel(II) bis(acetylacetonate) hydrate; 1,10-Phenanthroline / 1,4-dioxane; tetrahydrofuran / 0.17 h / 23 °C / Inert atmosphere; Sealed tube
2.2: 1 h / 23 °C / Inert atmosphere; Sealed tube
With
1,10-Phenanthroline; nickel(II) bis(acetylacetonate) hydrate; magnesium; lithium chloride;
In
tetrahydrofuran; 1,4-dioxane; ethylene dibromide;
2.1: |Negishi Coupling / 2.2: |Negishi Coupling;
DOI:10.1021/acs.orglett.1c04074
