3-Penten-2-ol, 3-methyl-

Base Information

• Chemical Name: 3-Penten-2-ol, 3-methyl-
• CAS No.: 2747-53-7
• Molecular Formula: C6H12O
• Molecular Weight: 100.161
• Mol file: 2747-53-7.mol

Synonyms:

Chemical Property of 3-Penten-2-ol, 3-methyl-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 3-Penten-2-ol, 3-methyl-

There total 3 articles about 3-Penten-2-ol, 3-methyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

3-methylpent-3-en-2-one (565-62-8) → 3-methylpentan-2-ol (565-60-6) + 3-methyl-3-penten-2-ol (2747-53-7)

Guidance literature:

With cis-[bis (1,10-phenanthroline) dichlororuthenium(II)]; potassium tert-butylate; hydrogen; In butan-1-ol; at 100 ℃; under 15301.5 Torr; chemoselective reaction; Autoclave;

DOI:10.1016/j.poly.2010.09.006

Reference yield:

(E)-3-methylpent-3-en-2-one (1567-73-3) → 3-methylpentan-2-ol (565-60-6) + (E)-3-methylpent-3-en-2-ol (2747-53-7,60041-33-0,64683-06-3,116262-32-9,24652-51-5)

Guidance literature:

With Li⁽¹⁺⁾*C₁₂H₂₈AlO₃^(1-); In hexane; toluene; at -78 ℃; for 3h; Yield given. Yields of byproduct given. Title compound not separated from byproducts; or (i-Bu)2AlH, THF/hexane;

DOI:10.1021/jo00184a010

Reference yield:

3-Methyl-cis-2-penten (922-62-3) → 3-hydroxy-3-methyl-1-pentene (918-85-4) + (E)-3-methylpent-3-en-2-ol (2747-53-7,60041-33-0,64683-06-3,116262-32-9,24652-51-5) + 3-methylenepentan-2-ol (2747-52-6)

Guidance literature:

With oxygen; sodium acetate; rose bengal; In ethanol; isopropyl alcohol; at 18 - 20 ℃; Irradiation;

DOI:10.1002/hlca.19780610805

upstream raw materials:

3-methylpent-3-en-2-one

3-Methyl-cis-2-penten

(E)-3-methylpent-3-en-2-one

Downstream raw materials:

trans-1-(2,3-dimethyloxiranyl)-ethanone

(2R,3R,E)-methyl 2-hydroxy-3,4-dimethyl-2-((E)-styryl)hex-4-enoate

(E)-tert-butyl[(3-methylpent-3-en-2-yl)oxy]diphenylsilane

(E)-N-acetyl-4-methyl-N'-(3-methylpent-3-en-2-yl)benzenesulfonohydrazide

Refernces

• 1、 Kim, Sunggak,Ahn, Kyo Han. "Ate Complex from Diisobutylaluminum Hydride and n-Butyllithium as a Powerful and Selective Reducing Agent for the Reduction of Selected Organic Compounds Containing Various Functional Groups". . p. 1717 - 1724. Retrieved 2007/10/02.