Ethanone, 1-(2-bromophenyl)-, oxime

Base Information

Chemical Name:Ethanone, 1-(2-bromophenyl)-, oxime
CAS No.:27760-49-2
Molecular Formula:C8H8BrNO
Molecular Weight:214.062
Hs Code.:
DSSTox Substance ID:DTXSID90355975
Mol file:27760-49-2.mol

Synonyms:N-[1-(2-bromophenyl)ethylidene]hydroxylamine;Ethanone, 1-(2-bromophenyl)-, oxime;1215858-72-2;27760-49-2;DTXSID90355975;DPLPRQURUMMJQY-UHFFFAOYSA-N;1-(2-Bromo-phenyl)-ethanone oxime;AKOS017263765

Suppliers and Price of Ethanone, 1-(2-bromophenyl)-, oxime

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of Ethanone, 1-(2-bromophenyl)-, oxime

Chemical Property:

XLogP3:2.6
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:1
Exact Mass:212.97893
Heavy Atom Count:11
Complexity:158

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(=NO)C1=CC=CC=C1Br

Technology Process of Ethanone, 1-(2-bromophenyl)-, oxime

There total 4 articles about Ethanone, 1-(2-bromophenyl)-, oxime which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 2039-88-5
2-bromostyrene

: 27760-49-2
1-(2-bromophenyl)ethanone oxime

Guidance literature:: With ethyl nitrite; tetraethylammonium borohydride; In benzene; for 25h; Ambient temperature;
DOI:10.1021/jo00256a001

Reference yield: 85.0%

: 2142-69-0
2-bromophenyl methyl ketone

: 27760-49-2
1-(2-bromophenyl)ethanone oxime

Guidance literature:: With hydroxylamine hydrochloride; silica gel; for 0.1h;
DOI:10.1080/00397919908086156

Reference yield:

: 6630-33-7
ortho-bromobenzaldehyde

: 27760-49-2
1-(2-bromophenyl)ethanone oxime

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) n-BuLi / 1.) THF, hexane, RT, 1.5 h, 2.) a) RT, 1 h, b) 65 deg C, 5 h

2: 93 percent / EtONO, Et₄NBH₄, ClCoIII(DH)2py / benzene / 25 h / Ambient temperature

With n-butyllithium; ethyl nitrite; tetraethylammonium borohydride; In benzene;
DOI:10.1021/jo00256a001