Di(tert-butylamino)phenylphosphine

Base Information

• Chemical Name: Di(tert-butylamino)phenylphosphine
• CAS No.: 15916-96-8
• Molecular Formula: C14H25 N2 P
• Molecular Weight: 252.34
• Hs Code.: 2929909090
• Mol file: 15916-96-8.mol

Synonyms:Phosphonousdiamide, N,N'-di-tert-butyl-P-phenyl- (7CI,8CI)

Chemical Property of Di(tert-butylamino)phenylphosphine

Chemical Property:

• Boiling Point: 319.3°Cat760mmHg
• PKA: 7.91±0.70(Predicted)
• Flash Point: 146.9°C
• PSA: 37.65000
• Density: g/cm³
• LogP: 4.18180

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Di(tert-butylamino)phenylphosphine

There total 4 articles about Di(tert-butylamino)phenylphosphine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

Dichlorophenylphosphine (644-97-3) + tert-butylamine (75-64-9) → bis(tertbutylamino)phenylphosphane (15916-96-8)

Guidance literature:

In diethyl ether; at 0 ℃;

DOI:10.1002/(SICI)1099-0682(199912)1999:12<2355::AID-EJIC2355>3.0.CO;2-H

Reference yield:

Dichlorophenylphosphine (644-97-3) + tert-butylamine (75-64-9) → tert-butylamine hydrochloride (10017-37-5) + bis(tertbutylamino)phenylphosphane (15916-96-8)

Guidance literature:

In benzene; at 0 ℃;

DOI:10.1039/b300035d

Reference yield:

→ bis(tertbutylamino)phenylphosphane (15916-96-8)

Guidance literature:

Dichlor-phenyl-phosphin, tert.Butylamin/Benzol;

DOI:10.1021/jo01038a511

upstream raw materials:

2-phenyl-1,3,2-benzodioxaphosphole

tert-butylamine

Dichlorophenylphosphine

Downstream raw materials:

N,N'-Di-tert-butyl-P-phenylphosphonyldiamid

Refernces

• 1、 Eichhorn, Bettina,Noeth, Heinrich,Seifert, Thomas. "(N-lithioamino)diorganophosphanes and bis(N- lithioamino)organophosphanes: Synthesis and structures". . p. 2355 - 2368. Retrieved 2007/10/03.