Benzenemethanol, a-phenyl-a-2-propynyl-

Base Information

• Chemical Name: Benzenemethanol, a-phenyl-a-2-propynyl-
• CAS No.: 29430-66-8
• Molecular Formula: C16H14O
• Molecular Weight: 222.287
• Mol file: 29430-66-8.mol

Synonyms:1-Hydroxy-1.1-diphenyl-butin-(3);1,1-Diphenyl-but-3-in-1-ol;1,1-diphenylbut-3-yn-1-ol;1,1-diphenyl-3-butyn-1-ol;1,1-Diphenyl-but-3-yn-1-ol;

Chemical Property of Benzenemethanol, a-phenyl-a-2-propynyl-

Chemical Property:

• Boiling Point: 132 °C (0.5 mmHg)
• PSA: 20.23000
• LogP: 2.94580

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Benzenemethanol, a-phenyl-a-2-propynyl-

There total 13 articles about Benzenemethanol, a-phenyl-a-2-propynyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

benzophenone (119-61-9) + propargyl bromide (106-96-7) → 1,1-diphenyl-but-3-yn-1-ol (29430-66-8)

Guidance literature:

With zinc; In tetrahydrofuran; for 0.5h;

Reference yield: 100.0%

benzophenone (119-61-9) + propargyl magnesium bromide (18295-60-8) → 1,1-diphenyl-but-3-yn-1-ol (29430-66-8)

Guidance literature:

In tetrahydrofuran; at 0 - 20 ℃; Inert atmosphere;

DOI:10.1002/ejoc.200800711

Reference yield: 90.0%

benzophenone (119-61-9) + 1,2-propanediene (463-49-0) → 1,1-diphenyl-but-3-yn-1-ol (29430-66-8)

Guidance literature:

With n-butyllithium; In diethyl ether; at -20 - 20 ℃; for 1h;

DOI:10.1016/S0040-4039(98)00727-8

upstream raw materials:

benzophenone

propargyl bromide

allenylmagnesium bromide

allenylzinc bromide

Downstream raw materials:

1-(4-nitro-phenyl)-1,5,5-triphenyl-pent-2-yne-1,5-diol

1,1-bis-(4-bromo-phenyl)-5,5-diphenyl-pent-2-yne-1,5-diol

10-hydroxy-10-(4-hydroxy-4,4-diphenyl-but-1-ynyl)-anthrone

1,1-diphenyl-1 buten-3-one