Silanediol, ethyl(4-methoxyphenyl)-

Base Information

• Chemical Name: Silanediol, ethyl(4-methoxyphenyl)-
• CAS No.: 297163-77-0
• Molecular Formula: C9H14O3Si
• Molecular Weight: 198.294
• DSSTox Substance ID: DTXSID00445694
• Nikkaji Number: J1.407.633F
• Wikidata: Q82264206
• Mol file: 297163-77-0.mol

Synonyms:Silanediol, ethyl(4-methoxyphenyl)-;297163-77-0;(4-Methoxyphenyl)ethylsilanediol;DTXSID00445694

Chemical Property of Silanediol, ethyl(4-methoxyphenyl)-

Chemical Property:

• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 3
• Exact Mass: 198.07122084
• Heavy Atom Count: 13
• Complexity: 153

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC[Si](C1=CC=C(C=C1)OC)(O)O

Technology Process of Silanediol, ethyl(4-methoxyphenyl)-

There total 1 articles about Silanediol, ethyl(4-methoxyphenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

(dichloro)(ethyl)(4-methoxyphenyl)silane (130952-94-2) → (4-methoxyphenyl)(ethyl)silanediol (297163-77-0)

Guidance literature:

With water; aniline; In diethyl ether; at 0 ℃;

DOI:10.1021/jo000679p

Reference yield: 99.0%

4-nitrobenzaldehdye (555-16-8) + (4-methoxyphenyl)(ethyl)silanediol (297163-77-0) → (4-methoxyphenyl)(4-nitrophenyl)methanol (842-58-0)

Guidance literature:

[Rh(OH)(cod)]2; In tetrahydrofuran; at 70 ℃; for 24h;

DOI:10.1055/s-2002-19786

Reference yield: 95.0%

iodobenzene (591-50-4) + (4-methoxyphenyl)(ethyl)silanediol (297163-77-0) → 4-methoxylbiphenyl (613-37-6)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; silver(l) oxide; In tetrahydrofuran; at 60 ℃; for 12h;

DOI:10.1021/jo000679p

upstream raw materials:

(dichloro)(ethyl)(4-methoxyphenyl)silane

Downstream raw materials:

4-methoxylbiphenyl

(furan-2-yl)-(4-methoxyphenyl)-methanol

4-methoxy-4'-nitrobenzophenone

(4-methoxyphenyl)(4-nitrophenyl)methanol