1,1-Dichloro-2-(dichloromethoxy)-1,2,2-trifluoroethane

Base Information

• Chemical Name: 1,1-Dichloro-2-(dichloromethoxy)-1,2,2-trifluoroethane
• CAS No.: 29771-98-0
• Molecular Formula: C3HCl4F3O
• Molecular Weight: 251.848
• DSSTox Substance ID: DTXSID20575402
• Wikidata: Q82464745
• Mol file: 29771-98-0.mol

Synonyms:1,1-Dichloro-2-(dichloromethoxy)-1,2,2-trifluoroethane;29771-98-0;DTXSID20575402;KWCQHRBEZYVVGV-UHFFFAOYSA-N

Chemical Property of 1,1-Dichloro-2-(dichloromethoxy)-1,2,2-trifluoroethane

Chemical Property:

• XLogP3: 3.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 3
• Exact Mass: 251.870410
• Heavy Atom Count: 11
• Complexity: 139

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(OC(C(F)(Cl)Cl)(F)F)(Cl)Cl

Technology Process of 1,1-Dichloro-2-(dichloromethoxy)-1,2,2-trifluoroethane

There total 2 articles about 1,1-Dichloro-2-(dichloromethoxy)-1,2,2-trifluoroethane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-chloro-1,1,2-trifluoroethyl methyl ether (425-87-6) → 2-chloro-1,1,2-trifluoroethyl chloromethyl ether (428-92-2) + (2-chloro-1,1,2-trifluoroethyl)dichloromethylether (428-96-6) + (2-chloro-1,1,2-trifluoroethyl)trichloromethylether (460-99-1) + dichloromethyl(2,2-dichloro-1,1,2-trifluoroethyl)ether (29771-98-0)

Guidance literature:

With chlorine; Irradiation;

DOI:10.1135/cccc19930565

Reference yield:

(2,2-dichloro-1,1,2-trifluoroethyl)trichloromethylether (428-73-9) → (2-chloro-1,1,2-trifluoroethyl)trichloromethylether (460-99-1) + dichloromethyl(2,2-dichloro-1,1,2-trifluoroethyl)ether (29771-98-0) + 3,6-dichloro-5,5,6-trifluoro-2-methyl-1-oxa-2-hexanol + 1,2-dichloro-1,2-bis(2-chloro-1,1,2-trifluoroethoxy)ethane + 1-chloro-1,2-bis(2-chloro-1,1,2-trifluoroethoxy)ethene + 1,2-dichloro-1,2-bis(2-chloro-1,1,2-trifluoroethoxy)ethene

Guidance literature:

With isopropyl alcohol; at 30 ℃; for 2.5h; Product distribution; Mechanism; Irradiation; other chlorofluoro ethers; other reducing agents alcohols and ethers; var. temp. and time;

DOI:10.1135/cccc19930565

Reference yield:

dichloromethyl(2,2-dichloro-1,1,2-trifluoroethyl)ether (29771-98-0) → (2-chloro-1,1,2-trifluoroethyl)dichloromethylether (428-96-6)

Guidance literature:

With tetrahydrofuran; Irradiation; var.reag.: i-PrOH, Et2O, 1,3-dioxolane, 2-BuOH, cyclohexanol, EtOH, 3-pentanol: var irr.: γ-ray of 60Co;

DOI:10.1016/S0022-1139(00)83388-6

upstream raw materials:

2-chloro-1,1,2-trifluoroethyl methyl ether

(2,2-dichloro-1,1,2-trifluoroethyl)trichloromethylether

Downstream raw materials:

(2-chloro-1,1,2-trifluoroethyl)dichloromethylether