BIS(CYCLOPENTADIENYL)DIFLUOROTITANIUM(IV)

Base Information

• Chemical Name: BIS(CYCLOPENTADIENYL)DIFLUOROTITANIUM(IV)
• CAS No.: 309-89-7
• Molecular Formula: C10H10 F2 Ti
• Molecular Weight: 216.066
• Hs Code.: 2931900090
• Mol file: 309-89-7.mol

Synonyms:Dicyclopentadienyltitanium(IV)difluoride (6CI); Titanium, difluorodicyclopentadienyl- (7CI); Bis(cyclopentadienyl)difluorotitanium;Bis(cyclopentadienyl)titanium difluoride; Bis(h5-cyclopentadienyl)difluorotitanium;Dicyclopentadienyldifluorotitanium; Difluorobis(cyclopentadienyl)titanium;Difluorotitanocene

Chemical Property of BIS(CYCLOPENTADIENYL)DIFLUOROTITANIUM(IV)

Chemical Property:

• Melting Point: 238-280°C dec
• Boiling Point: 41.5 °C at 760 mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: 2.88340

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of BIS(CYCLOPENTADIENYL)DIFLUOROTITANIUM(IV)

There total 31 articles about BIS(CYCLOPENTADIENYL)DIFLUOROTITANIUM(IV) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

dibromobis(cyclopentadienyl)titanium(IV) → titanocene difluoride (309-89-7)

Guidance literature:

With hydrogen fluoride; In not given; refluxing Ti-complex with excess HF for 15 min; pptn. on cooling, filtration, drying (vac.);

DOI:10.1016/S0020-1693(00)94100-8

Reference yield: 99.0%

((C5H5)2TiBr)2O → titanocene difluoride (309-89-7)

Guidance literature:

With hydrogen fluoride; In not given; treatment of Ti-complex with excess HF; washing (alcoholic HF), drying (vac.);

DOI:10.1016/S0020-1693(00)94100-8

Reference yield: 99.0%

((C5H5)2TiI)2O → titanocene difluoride (309-89-7)

Guidance literature:

With hydrogen fluoride; In not given; treatment of Ti-complex with excess HF; washing (alcoholic HF), drying (vac.);

DOI:10.1016/S0020-1693(00)94100-8

upstream raw materials:

bis(cyclopentadienyl)titanium dichloride

sodium fluoride

acetonitrile

tetrakis(actonitrile)copper(I) hexafluorophosphate

Downstream raw materials:

bis(cyclopentadienyl)titanium dichloride

Refernces

• 1、 King,Zipperer. "Organometallic transition metal derivatives containing fluorine. V. Some perfluoro-1-methylpropenyl derivatives of metal carbonyls and metal cyclopentadienyls". . p. 2119 - 2125. Retrieved 1972.
• 2、 Yu, Peihua,Murphy, Eamonn F.,Roesky, Herbert W.,Lubini, Paolo,Schmidt, Hans-Georg,Noltemeyer, Mathias. "New fluoride derivative of a dinuclear titanium (III) fulvalene complex: Crystal structure of [(η5-C5H5)Ti(μ-F)] 2(μ-η5:η5-C10H 8)". . p. 313 - 316. Retrieved 1997.
• 3、 Bares, Josef,Novak, Petr,Nadvornik, Milan,Jambor, Roman,Lebl, Tomas,Cisarova, Ivana,Ruzicka, Ales,Holecek, Jaroslav. "Monomeric triorganotin(IV) fluorides containing a C,N-chelating ligand". . p. 2967 - 2971. Retrieved 2004.
• 4、 Thewalt, Ulf,Klein, Heinz-Peter. "EIN ORGANOTITANKOMPLEX MIT ZWEI KOORDINATIV GEBUNDENEN WASSERMOLEKUELEN: (ClO4)2*3C4H8O". . p. 297 - 308. Retrieved 1980.
• 5、 -. "Process for the synthesis of prostaglandin derivatives". Page/Page column 17. . Retrieved 2010/11/24.