Tetrakis(acetonitrile)copper(I) hexafluorophosphate

Base Information

• Chemical Name: Tetrakis(acetonitrile)copper(I) hexafluorophosphate
• CAS No.: 64443-05-6
• Molecular Formula: C8H12CuF6N4P
• Molecular Weight: 372.72
• Hs Code.: 2926907090
• European Community (EC) Number: 672-617-9
• DSSTox Substance ID: DTXSID70983013
• Mol file: 64443-05-6.mol

Synonyms:(Cu(NCCH3))4PF6;tetrakis(acetonitrile)copper(I);tetrakis(acetonitrile)copper(I) hexafluorophosphate;tetrakis(acetonitrile)copper(I) perchlorate;tetrakis(acetonitrile)copper(I) tetrafluoroborate (1-)

Chemical Property of Tetrakis(acetonitrile)copper(I) hexafluorophosphate

Chemical Property:

• Melting Point: 160 °C (dec.)(lit.)
• PSA: 108.75000
• LogP: 5.49942
• Storage Temp.: Inert atmosphere,Store in freezer, under -20°C
• Sensitive.: air sensitive, moisture sensitiv
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 11
• Rotatable Bond Count: 0
• Exact Mass: 371.999974
• Heavy Atom Count: 20
• Complexity: 92

Purity/Quality:

98%,99%, ^*data from raw suppliers

Tetrakis(acetonitrile)copper(I) Hexafluorophosphate ^*data from reagent suppliers

Safty Information:

• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Metals -> Organic Compounds, Metal Salts
• Canonical SMILES: CC#N.CC#N.CC#N.CC#N.F[P-](F)(F)(F)(F)F.[Cu+]
• Uses: Tetrakis(acetonitrile)copper(I) hexafluorophosphate can be employed as a catalyst for the synthesis of triazolo[1,2-a]indazole-1,3,8-trione and 2H-indazolo[2,1-b]phthalazine-trione derivatives by the reaction of aryl aldehydes, dimedone and urazole or phthalhydrazide, respectively. It can also be used as a copper precursor:For the formation of Cu2S/CdS nanorod junctions by cationic exchange process.To synthesize monometallic copper macrocyclic biquinazoline ligand [Cu(Mabiq)].To prepare the cuprous complex [Cu(2-iQBO)(POP)]PF6]; where 2-iQBO=2-(1′-isoquinolyl)benzoxazole and POP=bis[2-(diphenylphosphino)phenyl]ether, which can form luminescent pseudo-polymorphs.For the synthesis of [Cu(NHC)2]PF6 complexes [(NHC = N-heterocyclic carbene] which can be further used in the hydrosilylation of carbonyl compounds.

Technology Process of Tetrakis(acetonitrile)copper(I) hexafluorophosphate

There total 4 articles about Tetrakis(acetonitrile)copper(I) hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

potassium hexafluorophosphate (17084-13-8) + copper(ll) sulfate pentahydrate + copper (12775-96-1,15158-11-9,15721-63-8,16941-75-6,17493-86-6,19498-52-3,20499-83-6,20499-84-7,20499-85-8,20499-86-9,20573-10-8,20573-11-9,21595-51-7,21595-52-8,22206-52-6,26445-28-3,28959-95-7,37362-93-9,39417-05-5,54603-16-6,54603-23-5,54603-32-6,54603-40-6,54603-48-4,54603-81-5,54603-89-3,56316-56-4,95985-91-4,122297-32-9,7440-50-8) + acetonitrile (75-05-8,26809-02-9) → tetrakis(actonitrile)copper(I) hexafluorophosphate (64443-05-6)

Guidance literature:

In water; at 100 ℃; for 0.5h; Sealed tube; Green chemistry;

DOI:10.1039/c8ra10564b

Reference yield:

Cu(1+)*2(C5H3NCH2NC5H4C5H4NCH2C6H4OC2H4OC2H4OC6H4C(C6H5)(C6H4C4H9)2)2(4+)*9PF6(1-)*2C28H40O10=CuC296H328N12O32P9F54 → (C5H3NCH2NC5H4C5H4NCH2C6H4OC2H4OC2H4OC6H4C(C6H5)(C6H4C(CH3)3)2)2(4+)*4PF6(1-)*C28H40O10=C120H124N6O6(PF6)4*C28H40O10 + tetrakis(actonitrile)copper(I) hexafluorophosphate (64443-05-6)

Guidance literature:

With ion-exchange resin Murochelate B-1; In acetone; treatment of the complex by suspn. of ion-exchange resin at pH 5.5; decompn. within 15 min; detn. by (1)H NMR;

DOI:10.1002/anie.200353534

Reference yield:

Cu(1+)*2(C5H3NCH2NC5H4C5H4NCH2C6H4OC2H4OC2H4OC6H4C(C6H5)(C6H4C4H9)2)2(4+)*9PF6(1-)*2C28H40O10=CuC296H328N12O32P9F54 → (C5H3NCH2NC5H4C5H4NCH2C6H4OC2H4OC2H4OC6H4C(C6H5)(C6H4C(CH3)3)2)2(4+)*4PF6(1-)*C28H40O10=C120H124N6O6(PF6)4*C28H40O10 + tetrakis(actonitrile)copper(I) hexafluorophosphate (64443-05-6)

Guidance literature:

With ion-exchange resin Murochelate B-1; In acetone; treatment of the complex by suspn. of ion-exchantge resin at pH 5.5; decompn. within 15 min; detd. by (1)H NMR;

DOI:10.1002/anie.200353534

upstream raw materials:

acetonitrile

potassium hexafluorophosphate

copper

Downstream raw materials:

bis(6-p-tolyl-2,2'-bipyridine)copper(I) hexafluorophosphate

Cu(C₃₄H₃₄N₂O₆)(C₃₈H₄₀N₂O₆)⁽¹⁺⁾*PF₆^(1-)=[Cu(C₃₄H₃₄N₂O₆)(C₃₈H₄₀N₂O₆)]PF₆

Cu(C₃₄H₃₄N₂O₆)(C₄₂H₄₈N₂O₈)⁽¹⁺⁾*PF₆^(1-)=[Cu(C₃₄H₃₄N₂O₆)(C₄₂H₄₈N₂O₈)]PF₆

bis(2-p-anisyl-1,10-phenanthroline)copper(I) hexafluorophosphate

Refernces

• 1、 Filonenko,Fayzullin,Khusnutdinova. "Intramolecular non-covalent interactions as a strategy towards controlled photoluminescence in copper(i) complexes". . p. 1638 - 1645. Retrieved 2017.