Methylhexadecyl sulfoxide

Base Information

• Chemical Name: Methylhexadecyl sulfoxide
• CAS No.: 3079-32-1
• Molecular Formula: C17H36OS
• Molecular Weight: 288.53200
• Mol file: 3079-32-1.mol

Synonyms:1-Methanesulfinyl-hexadecane;Hexadecyl-methyl-sulfoxid;Sulfoxide, hexadecyl methyl;n-hexadecyl methyl sulfoxide;hexadecyl-methyl sulfoxide;

Chemical Property of Methylhexadecyl sulfoxide

Chemical Property:

• PSA: 36.28000
• LogP: 6.71190

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Methylhexadecyl sulfoxide

There total 5 articles about Methylhexadecyl sulfoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

methyl n-hexadecyl sulfide (27563-68-4) → n-hexadecyl methyl sulfoxide (3079-32-1)

Guidance literature:

With sodium periodate; tetrabutylammomium bromide; In methanol; at 20 - 24 ℃; for 24h;

DOI:10.1080/00304940009356286

Reference yield: 64.0%

methyl 4-chlorophenyl sulfoxide (934-73-6) + hexadecylmagnesium bromide (872-26-4) → n-hexadecyl methyl sulfoxide (3079-32-1)

Guidance literature:

In tetrahydrofuran; at 0 ℃; for 1.5h;

DOI:10.1021/jo991912q

Reference yield:

C16H33OS(1-)*Na(1+) + methyl iodide (74-88-4) → n-hexadecyl methyl sulfoxide (3079-32-1)

Guidance literature:

In tetrahydrofuran; methanol; at -78 - 20 ℃;

DOI:10.1016/S0040-4039(03)01521-1

upstream raw materials:

methyl n-hexadecyl sulfide

methyl 4-chlorophenyl sulfoxide

hexadecylmagnesium bromide

methyl iodide

Refernces

• 1、 Yamamoto, Tamotsu,Hayakawa, Tetsushi,Yoshino, Mugi,Hata, Soh-Ichiroh,Hirayama, Yorinobu. "An efficient oxidation of long chain alkyl methyl sulfides to sulfoxides". . p. 192 - 196. Retrieved 2007/10/03.