methyl hydrogen carbonate

Base Information

• Chemical Name: methyl hydrogen carbonate
• CAS No.: 7456-87-3
• Molecular Formula: C2H4O3
• Molecular Weight: 76.052
• Mol file: 7456-87-3.mol

Synonyms:

Chemical Property of methyl hydrogen carbonate

Chemical Property:

• Vapor Pressure: 10.3mmHg at 25°C
• Boiling Point: 119.1°Cat760mmHg
• Flash Point: 54.9°C
• Density: 1.216g/cm³

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of methyl hydrogen carbonate

There total 2 articles about methyl hydrogen carbonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

<13CO>-N-methyl-N-nitrosourea (MNU) → diazomethane (186581-53-3,908094-01-9,334-88-3) + 13C urea (58069-82-2) + carbonic acid monomethyl ester (7456-87-3) + [13C]cyanic acid (118832-13-6) + carbonate ion + (13)CH2NO5P(2-)

Guidance literature:

With sodium hydroxide; phosphate buffer; In methanol; water; at 22 ℃; Product distribution; other reagents, temperature;

DOI:10.1016/S0040-4020(97)00018-5

Reference yield:

Fenbendazole (43210-67-9) → carbonic acid monomethyl ester (7456-87-3) + 5-(phenylthio)-1H-benzo[d]imidazol-2-amine (53065-28-4)

Guidance literature:

With hydrogenchloride; In ethanol; for 5h; UV-irradiation;

DOI:10.4067/S0717-97072013000300006

Reference yield: 79.0%

2,6-dimethylcyclohexanone (2816-57-1) + carbonic acid monomethyl ester (7456-87-3) → (+/-)-methyl 1,3-dimethyl-2-oxo-1-cyclohexanecarboxylate (84072-28-6)

Guidance literature:

With sodium hydride; In methanol; benzene; for 4.3h; Heating;

upstream raw materials:

Fenbendazole

Downstream raw materials:

(+/-)-methyl 1,3-dimethyl-2-oxo-1-cyclohexanecarboxylate

carbonic acid dimethyl ester

methyl chloroformate

(4-trifluoromethyl-phenyl)carbonyl-acetic acid methyl ester

Refernces

• 1、 Golding, Bernard T.,Bleasdale, Christine,McGinnis, Joseph,Mueller, Susanna,Rees, Hue Thu,Rees, Nicholas H.,Farmer, Peter B.,Watson, William P.. "The mechanism of decomposition of N-methyl-N-nitrosourea (MNU) in water and a study of its reactions with 2'-deoxyguanosine, 2'-deoxyguanosine 5'-monophosphate and d(GTGCAC)". . p. 4063 - 4082. Retrieved 2007/10/03.