Vanadium(3)fluoride

Base Information

• Chemical Name: Vanadium(3)fluoride
• CAS No.: 10049-12-4
• Molecular Formula: F3V
• Molecular Weight: 107.937
• UNII: O3S3Z32R8P
• Nikkaji Number: J134.239H
• Mol file: 10049-12-4.mol

Synonyms:Vanadium(3)fluoride;VANADIUM FLUORIDE (VF3);VANADIUM TRIFLUORIDE [MI];AKOS025293939

Chemical Property of Vanadium(3)fluoride

Chemical Property:

• Melting Point: 140°C
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: 1.26060
• Sensitive.: Moisture Sensitive
• Water Solubility.: Practically insoluble in water, acetone, and glacial acetic acid
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 107.939167
• Heavy Atom Count: 4
• Complexity: 0

Purity/Quality:

98%,99%, ^*data from raw suppliers

VANADIUM(III) FLUORIDE 95.00% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi,T
• Statements: 36/37/38-34-32-23/24/25
• Safety Statements: 26-36-45-36/37/39-22

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [F-].[F-].[F-].[V]
• Uses: Employed in oxygen-sensitive applications, such as metal production.

Technology Process of Vanadium(3)fluoride

There total 34 articles about Vanadium(3)fluoride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 21.6%

stannous fluoride + vanadium (7440-62-2) → tin (7440-31-5) + vanadium(III) fluoride (10049-12-4)

Guidance literature:

In melt; placing of mixt. of V with SnF2 (molar ratio SnF2:V=2.68) in Fluoroplast-4 ampule, closing by screwed stopper, exposition for 1.50 h at 240°C; various product ratio yields for various conditions; cooling, stirring up in water, collection, drying;

Reference yield: 4.0%

vanadium (7440-62-2) + hydrogen fluoride (7664-39-3,12381-92-9,32057-09-3,74835-82-8) → vanadium(III) fluoride (10049-12-4)

Guidance literature:

In neat (no solvent); 24 h in autoclave at 225°C and 10 atm (H2);;

DOI:10.1016/0022-1902(61)80382-5

Reference yield:

vanadia + Dichlorodifluoromethane (75-71-8) → vanadium(III) fluoride (10049-12-4) + carbon dioxide (124-38-9,18923-20-1)

Guidance literature:

In neat (no solvent); using a fixed-bed flow reactor system at atmospheric pressure; placing of of V2O3 in quartz reactor; heating at 723 K under 1% CCl2F2/He atmosphere with total flow rate of 30 ml/min for 5 h; monitoring by XRD and GC-TCD;

DOI:10.1246/bcsj.78.1565

upstream raw materials:

Dichlorodifluoromethane

vanadium

chlorine trifluoride

hydrogen fluoride

Downstream raw materials:

vanadium

Refernces

• 1、 Bentrup. "Thermal dehydration of the fluoride hydrates FeMIIIF5·7H2O (MIII = Al, Fe, V, Cr)". . p. 397 - 406. Retrieved 1996.
• 2、 Graulich,Babel. "Structural and magnetochemical studies of SrVF5". . p. 1223 - 1228. Retrieved 2003.
• 3、 Klimov,Kuz'menko,Legasov,Udalova. "SENSITIZED LUMINESCENCE OF VF5 UNDER THE ACTION OF THE EMISSION OF A PULSED CO2 LASER.". . p. 586 - 589. Retrieved 1980.
• 4、 Stout, J. W.,Boo, W. O. J.. "". . p. 1 - 8. Retrieved 1979.
• 5、 Reinhard, Christine,Kramer, Karl,Biner, Daniel A,Gudel, Hans U. "Cooperative radiative and nonradiative effects in K2NaScF6 codoped with V3+ and Er3+.". . p. 3374 - 3380. Retrieved 2004.
• 6、 Schmidt,Kraus,Mueller. "New Fluorozirconates and -hafnates with V2+ and Ti2+". . p. 2344 - 2350. Retrieved 2008/10/08.