Phosphoric acid, diethyl pentafluorophenyl ester

Base Information

• Chemical Name: Phosphoric acid, diethyl pentafluorophenyl ester
• CAS No.: 31839-59-5
• Molecular Formula: C10H10F5O4P
• Molecular Weight: 320.153
• Mol file: 31839-59-5.mol

Synonyms:

Chemical Property of Phosphoric acid, diethyl pentafluorophenyl ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Phosphoric acid, diethyl pentafluorophenyl ester

There total 5 articles about Phosphoric acid, diethyl pentafluorophenyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

diethyl cyanophosphonate (2942-58-7) + 2,3,4,5,6-pentafluorophenol (771-61-9) → diethyl pentafluorophenyl phosphate (31839-59-5)

Guidance literature:

With triethylamine; In dichloromethane; at 0 ℃; for 0.5h;

DOI:10.1080/00397919708005008

Reference yield: 73.6%

ethanol (64-17-5) + 2,3,4,5,6-pentafluorophenol (771-61-9) → diethyl pentafluorophenyl phosphate (31839-59-5)

Guidance literature:

2,3,4,5,6-pentafluorophenol; With triethylamine; In dichloromethane; for 0.0833333h; Inert atmosphere;

With trichlorophosphate; In dichloromethane; for 2.5h; Inert atmosphere; Cooling with ice;

ethanol; In dichloromethane; for 4.6h; Inert atmosphere;

Reference yield:

2,3,4,5,6-pentafluorophenol (771-61-9) + diethyl chlorophosphate (814-49-3) → diethyl pentafluorophenyl phosphate (31839-59-5)

Guidance literature:

With triethylamine; In benzene; at 70 - 80 ℃;

DOI:10.1021/jo00245a015

upstream raw materials:

2,3,4,5,6-pentafluorophenol

1-(Diethoxyphosphinyl)imidazole

diethyl chlorophosphate

diethyl cyanophosphonate

Downstream raw materials:

pentafluorophenolate anion

N-(diethoxyphosphoryl)imidazolium ion

diethyl methyl phosphate

2,3,4,5,6-pentafluorophenol