Methyl 2-(azidomethyl)benzoate

Base Information

Chemical Name:Methyl 2-(azidomethyl)benzoate
CAS No.:329781-57-9
Molecular Formula:C9H9N3O2
Molecular Weight:191.189
Hs Code.:
DSSTox Substance ID:DTXSID70573852
Nikkaji Number:J1.467.726G
Wikidata:Q82462696

Synonyms:methyl 2-(azidomethyl)benzoate;329781-57-9;SCHEMBL15353860;DTXSID70573852;KCXICZNCIHQORZ-UHFFFAOYSA-N;AKOS040814983;F78625;EN300-1603004;F2157-0561

Suppliers and Price of Methyl 2-(azidomethyl)benzoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Total 0 raw suppliers

Chemical Property of Methyl 2-(azidomethyl)benzoate

Chemical Property:

XLogP3:3.3
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:4
Exact Mass:191.069476538
Heavy Atom Count:14
Complexity:248

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC(=O)C1=CC=CC=C1CN=[N+]=[N-]

Technology Process of Methyl 2-(azidomethyl)benzoate

There total 6 articles about Methyl 2-(azidomethyl)benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 2417-73-4
methyl 2-bromomethylbenzoate

: 329781-57-9
methyl 2-(azidomethyl) benzoate

Guidance literature:: With sodium azide; In N,N-dimethyl-formamide; at 70 ℃; for 24h;
DOI:10.1039/c8dt04901g

Reference yield:

: 89-71-4
2-Methyl-benzoic acid methyl ester

: 329781-57-9
methyl 2-(azidomethyl) benzoate

Guidance literature:: Multi-step reaction with 2 steps

1: NBS / benzoyl peroxide / CCl₄ / 24 h / Heating

2: 4.58 g / NaN₃ / ethanol / 48 h / 20 °C

With N-Bromosuccinimide; sodium azide; dibenzoyl peroxide; In tetrachloromethane; ethanol;
DOI:10.1021/jo015987h