Propargyltrichlorosilane

Base Information

• Chemical Name: Propargyltrichlorosilane
• CAS No.: 33415-29-1
• Molecular Formula: C3H3Cl3Si
• Molecular Weight: 173.501
• DSSTox Substance ID: DTXSID20454203
• Nikkaji Number: J684.884B
• Wikidata: Q82275584
• Mol file: 33415-29-1.mol

Synonyms:Propargyltrichlorosilane;Silane, trichloro-2-propynyl-;33415-29-1;SCHEMBL2362407;GCGIEZRRYWQDIJ-UHFFFAOYSA-;DTXSID20454203;InChI=1/C3H3Cl3Si/c1-2-3-7(4,5)6/h1H,3H2

Chemical Property of Propargyltrichlorosilane

Chemical Property:

• PSA: 0.00000
• LogP: 2.27490
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 171.906960
• Heavy Atom Count: 7
• Complexity: 94.5

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C#CC[Si](Cl)(Cl)Cl

Technology Process of Propargyltrichlorosilane

There total 3 articles about Propargyltrichlorosilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 22.1%

2-propynyl chloride (624-65-7) → 1,1,1,3,3,3-hexachloro-1,3-disilapropane (4142-85-2) + trichloro(prop-2-ynyl)silane (33415-29-1) + Phenyltrichlorosilane (98-13-5) + 1,1,2,2-tetrachloro-1,2-disilacyclopent-4-ene

Guidance literature:

With hexachlorodisilane; at 520 ℃; for 0.00833333h; Further byproducts given;

Reference yield: 22.1%

2-propynyl chloride (624-65-7) → allyltrichlorosilane (107-37-9) + 1,1,1,3,3,3-hexachloro-1,3-disilapropane (4142-85-2) + trichloro(prop-2-ynyl)silane (33415-29-1) + 1,1,2,2-tetrachloro-1,2-disilacyclopent-4-ene

Guidance literature:

With hexachlorodisilane; at 520 ℃; for 0.00833333h; Further byproducts given;

Reference yield: 17.2%

2-propynyl chloride (624-65-7) → allyltrichlorosilane (107-37-9) + 1,1,1,3,3,3-hexachloro-1,3-disilapropane (4142-85-2) + trichloro(prop-2-ynyl)silane (33415-29-1) + Phenyltrichlorosilane (98-13-5) + 1,1,2,2-tetrachloro-1,2-disilacyclopent-4-ene

Guidance literature:

With hexachlorodisilane; at 450 ℃; for 0.00694444h; Product distribution; Mechanism; influence of temperature, ratio of reagents;

upstream raw materials:

2-propynyl chloride

Downstream raw materials:

1-phenylhexa-4,5-dien-3-ol

1-phenylbuta-2,3-dien-1-ol

1-(4-methoxylphenyl)buta-2,3-dien-1-ol

1-cyclohexylbuta-2,3-dien-1-ol