Allyltrichlorosilane

Base Information

• Chemical Name: Allyltrichlorosilane
• CAS No.: 107-37-9
• Molecular Formula: C3H5 Cl3 Si
• Molecular Weight: 175.517
• Hs Code.: 29319090
• European Community (EC) Number: 203-485-9
• NSC Number: 20940
• UN Number: 1724
• UNII: UB3N98803N
• DSSTox Substance ID: DTXSID3059347
• Nikkaji Number: J54.318G
• Wikipedia: Allyltrichlorosilane
• Wikidata: Q27290990
• Mol file: 107-37-9.mol

Synonyms:allyltrichlorosilane

Chemical Property of Allyltrichlorosilane

Chemical Property:

• Appearance/Colour: Clear colorless to slightly yellow liquid
• Vapor Pressure: 10 mm Hg ( 16.1 °C)
• Melting Point: 35℃
• Refractive Index: n20/D 1.443(lit.)
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: 1.625g/cm³
• LogP: 2.82770
• Storage Temp.: Flammables area
• Sensitive.: Moisture Sensitive
• Solubility.: soluble in MeCN, THF, CH2Cl2, toluene, benzene, etc.; not compatible with protic solvents, acetone, and other ketones. Dipolar aprotic solvents (DMF, DMSO, HMPA, etc.) coordinate Si, thereby increasing the reactivity of C3H5SiCl3 with electrophiles.
• Water Solubility.: Soluble in THF, toluene, benzene. Reacts with water.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 1
• Exact Mass: 173.922610
• Heavy Atom Count: 7
• Complexity: 65.1
• Transport DOT Label: Corrosive Flammable Liquid

Purity/Quality:

99% ^*data from raw suppliers

Allyltrichlorosilane 95% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: F,C
• Statements: 11-34
• Safety Statements: 16-26-33-36/37/39-43-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Toxic Gases & Vapors -> Chlorosilanes
• Canonical SMILES: C=CC[Si](Cl)(Cl)Cl
• Physical properties: bp 116°C/750 Torr; nD 1.4450; d 1.211.
• Uses: Intermediate for silicones, fiberous glass finishes. Allyltrichlorosilane acts as a reagent that produces homoallylic alcohols upon reaction with aldehydes in DMF. It is used to make silicones and glass fiber fininshes.

Technology Process of Allyltrichlorosilane

There total 31 articles about Allyltrichlorosilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

3-chloroprop-1-ene (107-05-1) → allyltrichlorosilane (107-37-9) + 1,1,1,3,3,3-hexachloro-1,3-disilapropane (4142-85-2) + Phenyltrichlorosilane (98-13-5) + 3-(Dichloro-trichlorosilanylmethyl-silanyl)-propene + 1,1,3,3-tetrachloro-1,3-disilacyclohex-4-ene (59361-35-2)

Guidance literature:

With hexachlorodisilane; at 500 ℃; for 0.00833333h; Product distribution; Mechanism;

Reference yield: 73.0%

3-chloroprop-1-ene (107-05-1) → allyltrichlorosilane (107-37-9)

Guidance literature:

With tetrachlorosilane; triethylamine; copper(l) chloride;

DOI:10.1021/ja00013a035

Reference yield: 72.0%

3-chloroprop-1-ene (107-05-1) → allyltrichlorosilane (107-37-9) + 1,3-bis(trichlorosilyl)propane (18171-50-1)

Guidance literature:

With trichlorosilane; tetra-n-butylphosphonium chloride; at 130 ℃; for 2h;

DOI:10.1021/ja005814u

upstream raw materials:

isoquinoline

3-chloropropyltrichlorosilane

E/Z-1,3-Dichloropropene

(n-pr-1-Cl)SiCl₃

Downstream raw materials:

Allylchlorodimethylsilane

allyldichloromethylsilane

triacetoxyallylsilane

all(ph-4-Cl)SiCl₂

Refernces

• 1、 Calas, Raymond,Dunogues, Jacques,Deleris, Gerard,Duffaut, Norbert. "SOME PRACTICAL USES OF THE DISILANE RESIDUE FROM THE DIRECT SYNTHESIS OF METHYLCHLOROSILANES". . p. 117 - 130. Retrieved 1982.
• 2、 Furuya,Sukawa. "". . p. C1. Retrieved 1975.
• 3、 -. "PRODUCTION METHOD FOR LINEAR AND CYCLIC TRISILAALKANE". Page/Page column 6. . Retrieved 2011/04/19.
• 4、 Li, Zhifang,Cao, Xiaojun,Lai, Guoqiao,Liu, Jinhua,Ni, Yong,Wu, Jirong,Qiu, Huayu. "Controlled introduction of allylic group to chlorosilanes". . p. 4740 - 4746. Retrieved 2007/10/03.