Technology Process of 1-Bromo-2,8,9-trioxa-5-aza-1-silabicyclo[3.3.3]undecane
There total 1 articles about 1-Bromo-2,8,9-trioxa-5-aza-1-silabicyclo[3.3.3]undecane which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
tetrabutylammonium triphenyldifluorosilicate;
In
chloroform;
at 20 ℃;
for 168h;
Further Variations:;
Reagents;
Solvents;
reaction time;
Product distribution;
DOI:10.1002/hc.10211
- Guidance literature:
-
phenylacetylene;
With
n-butyllithium;
In
diethyl ether; hexane;
for 0.25h;
Heating;
1-bromosilatrane;
In
diethyl ether; hexane;
for 8h;
Heating;
DOI:10.1002/hc.10211
- Guidance literature:
-
In
acetonitrile;
byproducts: O2NOSi(OCH2CH2)3N; soln. of metal salt in MeCN added dropwise to soln. of silatrane in MeCN; ppt. sepd. by decanting (LiBr); concd. (vac.); residue dried (vac.); silatranyl nitrate was obtained;
DOI:10.1007/s11172-006-0326-8
