7550-35-8

Basic information

• Product Name: Lithium bromide
• Synonyms: Lithium bromide;lithiummonobromide;lithiun bromide;LiBr;thiuM broMide;ithium bromide;LITHIUM HALIDE;Lithium Bromide 99.;Lithiumbromide;Lithiumbromid
• CAS NO: 7550-35-8
• Molecular Formula: BrLi
• Molecular Weight: 86.845
• EINECS: 231-439-8
• Mol File: 7550-35-8.mol
• Article Data: 25

Chemical Properties

• Melting Point: 550℃
• Boiling Point: 1265 °C
• Flash Point: 1265 °C
• Appearance: White powder
• Density: 1.57 g/mL at 25 °C
• Water Solubility: 61 g/100 mL (25℃)
• CAS DataBase Reference: Lithium bromide(CAS DataBase Reference)
• NIST Chemistry Reference: Lithium bromide(7550-35-8)
• EPA Substance Registry System: Lithium bromide(7550-35-8)

Safety Data

• Hazard Codes: Xn:Harmful
• Statements: R22:
• Safety Statements: S16:Keep away from sources of ignition - No smoking.; S36/37/39:Wear suitable protective clothing, gloves and eye/face pr
• Hazardous Substances Data: 7550-35-8(Hazardous Substances Data)

Usage

Chemical Description

Lithium bromide is mentioned in the acknowledgment section as a component of a material used in the study.

InChI:InChI=1/BrH.Li/h1H;/q;+1/p-1

Synthetic route

lithium tetra-tert-butoxytitanate * THF + t-BuOMgBr → magnesium penta-tert-butoxytitanate + lithium bromide (7550-35-8)

Conditions	Yield
In tetrahydrofuran Ar atmosphere; 20°C; solvent removal (vacuum), extraction (hexane), crystn. (20°C, 40 h); elem. anal.;	A 25% B 100%

lithium tetra-tert-butoxytitanate * THF + magnesium bromide → magnesium bis(tetra-tert-butoxytitanate) + lithium bromide (7550-35-8)

Conditions	Yield
In tetrahydrofuran Ar atmosphere; 20°C; solvent removal (vacuum), extraction (hexane), crystn. on cooling (-78°C); elem. anal.;	A 33% B 100%

bromopentacarbonylmanganese(I) (14516-54-2) + [C6H5S(O)CH2](1-)*Li(1+)=[C6H5S(O)CH2]Li (59501-96-1) → dimanganese decacarbonyl (10170-69-1) + racemic methyl phenyl sulfoxide (1193-82-4) + diphenyldisulfane (882-33-7) + lithium bromide (7550-35-8)

Conditions	Yield
In tetrahydrofuran mixing reactants in THF at -78°C, slow warming to room temp.; evapn. in vac., extn. with pentane, ether and finally acetone or CH2Cl2, concn., chromy. on Al2O3, purifn. by crystn., distn. or sublimation;	A 87% B 41% C 40% D 93%

1-lithio-2,4,6-trimethylborazine + phosphorus tribromide (7789-60-8) → bromobis(2,4,6-trimethylborazinyl)phosphane (1064704-42-2) + lithium bromide (7550-35-8)

Conditions	Yield
In diethyl ether; hexane under inert gas; soln. of borazine (3.26 mmol) in mixt. of hexane (10 ml) and Et2O (10 ml) added to soln. of PBr3 (1.63 mmol) in hexane; stirredovernight; LiBr removed by filtration; evapd. (vac.) by 2/3 of volume; kept (5°C, wk); elem. anal.;	A 80% B 90%

2,2,6,6-tetramethyl-piperidine (768-66-1) + gallium(III) bromide (13450-88-9) → bis(2,2,6,6-tetramethylpiperidino)gallium bromide + lithium bromide (7550-35-8)

Conditions	Yield
With n-butyllithium In diethyl ether; hexane under inert atmosphere, piperidine in hexane reacted with n-BuLi in hexane, dropwise addn. of GaBr3 in diethyl ether at room temp., refluxed for 30 min, stirred at room temp. for 12 h; evapn. of solvent, taken up in pentane, filtered, evapd. in vac.; elem. anal.;	A 88% B n/a

C14H16NO2(1+)*Br(1-) + lithium trifluoromethanesulfonate (33454-82-9) → C14H16NO2(1+)*CF3O3S(1-) + lithium bromide (7550-35-8)

Conditions	Yield
In water at 20℃; for 1h;	A 87% B n/a

1,2-bis(diethylamino)diboron dibromide (101315-57-5) + dilithium N,N'-dimethylethylenediaminate (54760-74-6, 98900-11-9) → 2,3-bis(diethylamino)-1,4-dimethyl-1,4,2,3-diazadiborinane (158752-93-3) + lithium bromide (7550-35-8)

Conditions	Yield
In hexane under N2, addn. of B-compd. in hexane to Li-compd. in hexane at -60°C with stirring, allowed to warm up to room temp., kept for 30 min at reflux; solid material sepd., distd.; elem. anal.;	A 86% B n/a

C13H14NO(1+)*Br(1-) + lithium trifluoromethanesulfonate (33454-82-9) → C13H14NO(1+)*CF3O3S(1-) + lithium bromide (7550-35-8)

Conditions	Yield
In water at 20℃; for 1h;	A 85% B n/a

aluminium bromide (7727-15-3) + neopentyl lithium (7412-67-1) → tris(neopentyl)aluminium (42916-36-9) + lithium bromide (7550-35-8)

Conditions	Yield
In hexane Addn. of neopentyllithium to a suspn. of AlBr3 in hexane at 0°C in 20 min under protective gas, refluxing (3 h).; Vac. distn. of hexane, sepn. of Al-compd. from LiBr by flask to flask vac. distn. at 120°C. Short-path vac. distn., elem. anal., mol wt.;	A 82.3% B n/a

1,3-dibromo-1,2,3-tris(dimethylamino)triborane(5) (133911-59-8) → 1,3-bis(tert-butylamino)-1,2,3-tris(dimethylamino)triborane(5) (158819-19-3) + lithium bromide (7550-35-8)

Conditions	Yield
With LiNHCMe3 In toluene anhydrous and oxygen-free condns., addn. of Li-compd. in toluene to a stirred soln. of B-compd. in toluene at -78°C within 10 min, allowed to attain ambient temp., reaction time: 3 h; centrifuged, evapn. of solvent in vac., crystn. (pentane/toluene, -78°C); elem. anal.;	A 81% B n/a

dibromomethylborane (17933-16-3) + N-ethyl-N'-methylethane-1,2-diamine (111-37-5) → 1-ethyl-2,3-dimethyl-1,3,2-diazaborolidine (129920-21-4) + lithium bromide (7550-35-8)

Conditions	Yield
With n-butyllithium In diethyl ether; hexane byproducts: butane; under N2, diamine in petroleum ether and diethyl ether cooled to 0°C, dropwise addn. of n-BuLi in hexane, warmed to room temp., stirred for 10 h, boiled for 6 h under reflux, cooled to -78°C, addn. of CH3BBr2 in petroleum ether, warmed; solvent distd. off, volatiles condensed into a trap (-196°C) at 80°C, distn.; elem. anal.;	A 72% B n/a

triisopropylgermyllithium (43106-46-3) + [Fe(η-cyclopentadienyl)(CO)2(HgBr)] → {(η-cyclopentadienyl)Fe(CO)2}2Hg + bis(triisopropylgermyl)mercury (24004-54-4) + mercury + lithium bromide (7550-35-8)

Conditions	Yield
In toluene addn. of Li-compound in toluene at -30°C to Fe-compound in toluene, after 0.5h the temp. was raised to 20°-C; separation of Hg, removal of solvent in vac., addn. of hexane to the residue, pptn., removal of LiBr by washing with H2O;	A 56.5% B n/a C 19% D 71%

1,3-dibromo-1,2,3-tris(dimethylamino)triborane(5) (133911-59-8) → 1,2,3-tris(dimethylamino)-1,3-dipiperidinotriborane(5) (158819-06-8) + lithium bromide (7550-35-8)

Conditions	Yield
With LiNC5H10 In cyclohexane anhydrous and oxygen-free condns., addn. of Li-compd. in cyclohexane to a stirred soln. of B-compd. in cyclohexane within 20 min, stirred for 6 h; centrifuged, evapn. of solvent in vac., dissolved in hexane, cooled to -78°C; elem. anal.;	A 71% B n/a

dibromomethylborane (17933-16-3) + N,N-diisopropyl-1,2-ethanediamine (4013-94-9) → 1,3-diisopropyl-2-methyl-1,3,2-diazaborolidine (129920-20-3) + lithium bromide (7550-35-8)

Conditions	Yield
With n-butyllithium In diethyl ether; hexane byproducts: butane; under N2, diamine in petroleum ether and diethyl ether cooled to 0°C, dropwise addn. of n-BuLi in hexane, warmed to room temp., stirred for 10 h, boiled for 6 h under reflux, cooled to -78°C, addn. of CH3BBr2 in petroleum ether, warmed; solvent distd. off, volatiles condensed into a trap (-196°C) at 80°C, distn.; elem. anal.;	A 69% B n/a

indium(I) bromide + (tris-(trimethylsilyl)methyl)lithium bis(tetrahydrofuran) → tetrahedra-tetrakis[tris(trimethylsilyl)methyl]tetraindane(4) + lithium bromide (7550-35-8)

Conditions	Yield
In toluene Ar-atmosphere; addn. of Li-adduct to suspn. of InBr (-50°C), stirring, warming to room temp.; filtration (LiBr removal); washing (pentane), evapn. (vac.), crystn. (-50°C);	A 69% B n/a

dibromomethylborane (17933-16-3) + N,N'-diethylethylenediamine (111-74-0) → 1,3-diethyl-2-methyl-1,3,2-diazaboracyclopentane (6063-64-5) + lithium bromide (7550-35-8)

Conditions	Yield
With n-butyllithium In diethyl ether; hexane byproducts: butane; under N2, diamine in petroleum ether and diethyl ether cooled to 0°C, dropwise addn. of n-BuLi in hexane, warmed to room temp., stirred for 10 h, boiled for 6 h under reflux, cooled to -78°C, addn. of CH3BBr2 in petroleum ether, warmed; solvent distd. off, volatiles condensed into a trap (-196°C) at 80°C, distn.;	A 63% B n/a

1,4-dibrom-1,2,3,4-tetrakis(dimethylamino)tetraborane(6) (158819-22-8) → 1,4-bis(tert-butylamino)-1,2,3,4-tetrakis(dimethylamino)tetraborane(6) (158819-07-9) + lithium bromide (7550-35-8)

Conditions	Yield
With LiNHCMe3 In hexane anhydrous and oxygen-free condns., addn. of Li-compd. in hexane to a soln. of B-compd. in hexane at -60°C within 10 min, allowed to reach ambient temp., stirred for 5 h; centrifuged, evapn. of solvent in vac., recrystn. (pentane/toluene (10:1), -78°C); elem. anal.;	A 63% B n/a

1,4-dibrom-1,2,3,4-tetrakis(dimethylamino)tetraborane(6) (158819-22-8) → 1,2,3,4-tetrakis(dimethylamino)-1,4-bis(diphenylphosphanyl)tetraborane(6) (158819-09-1) + lithium bromide (7550-35-8)

Conditions	Yield
With LiPPh2 In toluene anhydrous and oxygen-free condns., addn. of Li-compd. in toluene to a soln. of B-compd. in toluene at -60°C, stirred for 2 d at ambient temp.; filtered, evapn. of solvent in vac., dissolved in pentane, cooled to -78°C for 14 d; elem. anal.;	A 57% B n/a

{bromo(di-isopropylamino)boryl}-tert-butyl(dibromophosphino)amine (112794-90-8) + diisopropylamine (108-18-9) → {bromo(di-isopropylamino)boryl}-{bromo(di-isopropylamino)phosphino}-tert-butylamine (112817-48-8) + lithium bromide (7550-35-8)

Conditions	Yield
With lithium butanide In diethyl ether; hexane addn. of soln. of i-Pr2NH in ether and soln. of Li-butanide in hexane at 20°C to B-compound at 0°C, stirred for 2 h at room temp.; filtration, removal of solvent, recrystn. from hexane at -70°C; elem. anal.;	A 55% B n/a

{bromo(di-isopropylamino)boryl}-{bromo(di-isopropylamino)phosphino}-tert-butylamine (112817-48-8) + lithium (7439-93-2) → 1-tert-butyl-2,3-bis(di-isopropylamino)-1,2,3-azaphosphaboriridine (112795-10-5) + lithium bromide (7550-35-8)

Conditions	Yield
In tetrahydrofuran stirred at 0°C for 3 h; evapn. to dryness, dissolved in hexane, filtration, distn. of filtrate (from ether at -70°C); elem. anal.;	A 54% B n/a

lithium nitride + ammonia (7664-41-7) + gallium(III) bromide (13450-88-9) → gallium nitride + lithium bromide (7550-35-8)

Conditions	Yield
In xylene Ar-atmosphere; heating for 80 h, solvent removal, heating at 450°C in vac., heatin at 500°C in NH3 flow overnight; detd. by X-ray diffraction, elem. anal., HRTEM, XPS;	A 53% B n/a

dibromomethylborane (17933-16-3) + N,N`-dimethylethylenediamine (110-70-3) → 1,2,3-trimethyl-[1,3,2]diazaborolidine (29173-12-4) + lithium bromide (7550-35-8)

Conditions	Yield
With n-butyllithium In diethyl ether; hexane byproducts: butane; under N2, diamine in petroleum ether and diethyl ether cooled to 0°C, dropwise addn. of n-BuLi in hexane, warmed to room temp., stirred for 10 h, boiled for 6 h under reflux, cooled to -78°C, addn. of CH3BBr2 in petroleum ether, warmed; solvent distd. off, volatiles condensed into a trap (-196°C) at 80°C, distn.;	A 52% B n/a

lithium pentafluorobenzenesulfinate (36649-96-4) + mercury dibromide → pentafluorophenylmercury bromide (828-72-8) + lithium bromide (7550-35-8)

Conditions	Yield
In water in aq. suspension at 25°C, molar ratio of LiOS(O)C6F5 and Hg comp. = 1.0:1.1, 2 h;	A 52% B n/a
In water in aq. suspension at 25°C, molar ratio of LiOS(O)C6F5 and Hg comp. = 1.0:1.1, 2 h;	A 52% B n/a

n-butyllithium (109-72-8, 29786-93-4) + bis[bis(trimethylsilyl)methyl]gallium bromide (141120-24-3) + imidotetraphenyldiphosphinic acid (31239-06-2) → bis[bis(trimethylsilyl)methyl]-imidotetraphenyldiphosphinato-O,O'-gallium + lithium bromide (7550-35-8)

Conditions	Yield
In diethyl ether; hexane; pentane Ar atm.; molar ratio (Ph2PO)2NH:BuLi 1:1, stirring (-50°C), heating (2 h, room temp.), stirring (2 h), cooling (-20°C), stirring (1 h, room temp.); evapn. (vac.), drying (vac.), extraction (n-pentane), filtn., concn., crystn. (-50°C);	A 48% B n/a

1,3-dibromo-1,2,3-tris(dimethylamino)triborane(5) (133911-59-8) → 1,3-di-tert-butyl-1,2,3-tris(dimethylamino)triborane(5) (158819-20-6) + lithium bromide (7550-35-8)

Conditions	Yield
With Li-t-Bu In hexane anhydrous and oxygen-free condns., addn. of t-BuLi in hexane to a stirred soln. of B-compd. in hexane at -78°C, stirred at ambient temp. for 7 d; filtered, reduced in volume, cooled to -78°C; elem. anal.;	A 46% B n/a

1,4-dibrom-1,2,3,4-tetrakis(dimethylamino)tetraborane(6) (158819-22-8) → 1,4-di-tert-butyl-1,2,3,4-tetrakis(dimethylamino)tetraborane(6) (158819-12-6) + lithium bromide (7550-35-8)

Conditions	Yield
With Li-t-Bu In hexane anhydrous and oxygen-free condns., addn. of t-BuLi in hexane to a stirred soln. of B-compd. in petroleum ether at -78°C, warmed to ambient temp., stirred at ambient temp. for 7 d; filtered, reduced in volume, cooled to -78°C;	A 40% B n/a

dibromomethylborane (17933-16-3) + N-isopropylethane-1,2-diamine (19522-67-9) → 1-isopropyl-2-methyl-1,3,2-diazaborolidine (129920-24-7) + lithium bromide (7550-35-8)

Conditions	Yield
With n-butyllithium In diethyl ether; hexane byproducts: butane; under N2, diamine in petroleum ether and diethyl ether cooled to 0°C, dropwise addn. of n-BuLi in hexane, warmed to room temp. (evapn. of butane), cooled to -78°C, dropwise addn. of CH3BBr2 in petroleum ether, warmed to room temp.; solvent distd. off, condensed into a trap (-196°C) at 80°C;	A 37% B n/a

3-bromo-4,5-diethyl-1,2,3-dithiaborole (91573-48-7) + ethylmagnesium bromide (925-90-6) + lithium hexamethyldisilazane (4039-32-1) → 3,4,5-triethyl-1,2,3-dithiaborole (124324-55-6) + lithium bromide (7550-35-8) + magnesium bromide

Conditions	Yield
In diethyl ether; hexane addn. of Grignard reagent to soln. of borole in hexane (N2, -80°C), slow warming; decantation, distn., addn. of LiN(SiMe3)2 to soln. of crude distillate (hexane, 0°C), refluxing (2h), decantation, solvent evapn., distn. (high vac.); elem. anal.;	A 36% B n/a C n/a

1,3-dibromo-1,2,3-tris(dimethylamino)triborane(5) (133911-59-8) → 1,3-dibutyl-1,2,3-tris(dimethylamino)triborane(5) (133911-59-8) + lithium bromide (7550-35-8)

Conditions	Yield
With BuLi In hexane anhydrous and oxygen-free condns., addn. of BuLi in hexane to a stirred soln. of B-compd. in hexane, warmed to ambient temp., stirred overnight; filtered, removal of solvent in vac., kept in vac. for 3 h; elem. anal.;	A 36% B n/a

3-bromo-4,5-diethyl-1,2,3-dithiaborole (91573-48-7) + isopropylmagnesium bromide (920-39-8) + lithium hexamethyldisilazane (4039-32-1) → 4,5-diethyl-3-i-propyl-1,2,3-dithiaborole (124324-56-7) + lithium bromide (7550-35-8) + magnesium bromide

Conditions	Yield
In diethyl ether; hexane addn. of Grignard reagent to soln. of borole in hexane (N2, -80°C), slow warming; decantation, distn., addn. of LiN(SiMe3)2 to soln. of crude distillate (hexane, 0°C), refluxing (2h), decantation, solvent evapn., distn. (high vac.); elem. anal.;	A 31% B n/a C n/a

sodium tetrahydroborate (16940-66-2) + lithium bromide (7550-35-8) → lithium borohydride

Conditions	Yield
In tetrahydrofuran byproducts: sodium bromide; under N2, soln. of LiBr and NaBH4 (molar ratio 1:1) in THF stirred withglass beads at 67°C (refluxed) for 8 h;	100%
In tetrahydrofuran byproducts: sodium bromide; under N2, soln. of LiBr and NaBH4 (molar ratio 1:1) in THF stirred withmagnetic stirrer at 67°C (refluxed) for 16 h;	99%
In diethyl ether byproducts: sodium bromide; under N2, soln. of LiBr in Et2O stirred with magnetic stirrer for 2 min, 1 equiv of NaBH4 introduced, maintained at 35°C with stirring for 32 h;	99%

(η5-pentamethylcyclopentadienyl){η4-(E)-2-methylpenta-1,3-diene}ruthenium chloride (140411-29-6) + lithium bromide (7550-35-8) → {(C5(CH3)5)Ru(C5H7(CH3))Br} (140411-41-2)

Conditions	Yield
In methanol dissolving the Ru complex in methanol under N2, treating with LiBr; filtration after 6 h, cooling (-30°C), crystn.; elem. anal.;	100%

(C6H4N2C3H4C6H5Pd(O2CCH3))2 + lithium bromide (7550-35-8) → (C6H4N2C3H4C6H5PdBr)2

Conditions	Yield
In methanol A mixt. of reagents in methanol was heated at reflux for 6 h, then stirred at room temp. for 1 h;; ppt. was washed with MeOH and Et2O; elem. anal.;;	100%

(η5-1-methylpentadienyl)(η5-pentamethylcyclopentadienyl)cobalt(III) hexafluorophosphate + lithium bromide (7550-35-8) → (η3-trans-1-methylpentadienyl)(η5-pentamethylcyclopentadienyl)cobalt(III) bromide

Conditions	Yield
In acetone LiBr added at room temp. to stirred soln. of Co complex in acetone; reacted at room temp. for 30 min; solvent removed in vac.; dissolved in min. amt. of benzene; filtered through Celite; solvent removed; dried under vac.;	100%

bis(1,5-cyclooctadiene)nickel (0) (1295-35-8) + 2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-4-trifluoromethylphenyl triflate + lithium bromide (7550-35-8) + tricyclohexylphosphine (2622-14-2) → trans-bromo[2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-4-trifluoromethylphenyl][bis(tricyclohexylphosphine)]nickel(II)

Conditions	Yield
In tetrahydrofuran at 20℃; for 2h; Inert atmosphere;	100%

bis(1,5-cyclooctadiene)nickel (0) (1295-35-8) + 3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)naphthalen-2-yl trifluoromethanesulfonate (1437769-76-0) + lithium bromide (7550-35-8) + triethylphosphine (554-70-1) → trans-bromo[3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)naphthalen-2-yl][bis(triethylphosphine)]nickel(II)

Conditions	Yield
In tetrahydrofuran; hexane at 20℃; for 1h; Inert atmosphere;	100%

trans-{PdCl2(1C-diphenylphosphinomethyl-2C-methyl-o-carborane)2 (130214-50-5) + lithium bromide (7550-35-8) → 2Pd(2+)*2Cl(1-)*2B10H8C2(CH3)CH2P(C6H5)2(2-)*2H(1+) = {PdCl(B10H9C2(CH3)CH2P(C6H5)2)}2

Conditions	Yield
In propan-1-ol refluxing Pd-complex and 10-fold excess of LiBr in propanol until soln. fading, pptn. on cooling; filtration, washing (water, MeOH, hexane), drying; elem. anal.; isomer product mixt. not sepd.;	99%

N,N-dimethyl-3-furancarboselenoamide (127802-49-7) + lithium bromide (7550-35-8) + palladium dichloride → PdBr(N,N-dimethyl-furan-3-carboselenoamido)

Conditions	Yield
In methanol stirred overnight at room temp.; ppt. collected, washed (MeOH), dried (air); elem.anal.;	99%

(η(5)-C5H4CH2CH2OSO2C6H4CH3)Mn(CO)3 (215460-58-5) + lithium bromide (7550-35-8) → (η(5)-C5H4CH2CH2Br)Mn(CO)3 (215460-59-6)

Conditions	Yield
In acetone byproducts: lithium tosylate; N2-atmosphere; refluxing Mn-complex with slight excess of LiBr overnight; evapn., extn. into CH2Cl2, filtration off of Li-tosylate (Celite), chromy. (SiO2, CH2Cl2);	99%

trans-[PdCl2(P{(CH2)14}3P)] (887279-82-5) + lithium bromide (7550-35-8) → trans-[PdBr2(P{(CH2)14}3P)] (887279-84-7)

Conditions	Yield
In tetrahydrofuran	99%
In tetrahydrofuran at 20℃; for 0.5h; Inert atmosphere;	99%

BeLiO4P + lithium bromide (7550-35-8) → Lithiumbromoberyllophosphat

Conditions	Yield
With H2O In water High Pressure; starting materials and H2O placed in gold ampoule, sealed, heated (autoclave, 36h, 550°C, 3723 bar), cooled in an oven in 6h to room temp.; washed, dried;;	98.5%

[(η(5)-pentamethylcyclopentadienyl)RuCl]4 + 1,2,3-triphenylcyclopropenyl bromide (23147-72-0) + lithium bromide (7550-35-8) → (η5-pentamethylcyclopentadienyl)(η3-triphenylcyclopropenyl)dibromoruthenium(IV)

Conditions	Yield
In tetrahydrofuran under N2; a THF soln. of the Ru complex, triphenylcyclopropenyl bromide and LiBr was stirred overnight; solvent was removed under reduced pressure, extd. with CH2Cl2, filtered, CH2Cl2 was removed under reduced pressure, chromy. on silica gel; elem. anal.;	98.5%

bis(1,5-cyclooctadiene)nickel (0) (1295-35-8) + 2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl trifluoromethanesulfonate (1437769-72-6) + lithium bromide (7550-35-8) + tricyclohexylphosphine (2622-14-2) → trans-bromo[2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl][bis(tricyclohexylphosphine)]nickel(II) (447405-44-9)

Conditions	Yield
In tetrahydrofuran at 20℃; for 2h; Inert atmosphere;	98.2%

μ-dichloro bis-(1,2,6-η3-4-t-butyl-1-methylcyclohexenyl) dipalladium + lithium bromide (7550-35-8) → μ-dibromo bis-(1,2,6-η3-4-t-butyl-1-methylcyclohexenyl) dipalladium

Conditions	Yield
In not given from corresponding dichloro complex by exchange with LiBr by the method of Robinson and Shaw, J. Chem. Soc., 1964, 5002; chromy. (CH2Cl2, on SiO2), recrystn. (petroleum ether);	98%

[PtCl2(P(OC6H4OCH3)3)2] (144613-92-3) + lithium bromide (7550-35-8) → [PtBr2(P(OC6H4OCH3)3)2] (176510-13-7)

Conditions	Yield
In dichloromethane (N2); stirring (2 h); concn. (vac.), pptn. with EtOH, filtration, washing (H2O; EtOH; pentane), drying (vac.); elem. anal.;	98%

(C4HN(adamantyl)Me2(2,6-diisopropylphenyl))AuCl + lithium bromide (7550-35-8) → C27H39AuBrN

Conditions	Yield
With air In acetone at 20℃; for 24h;	98%

(1,3-bis(3'-butylimidazol-2'-ylidene)benzene)disilver(I) dichloride + lithium bromide (7550-35-8) → bis(μ-1,3-bis(3'-butylimidazol-2'-ylidene)benzene-k-C)tetra-μ3-bromotetrasilver(I)

Conditions	Yield
In acetone Inert atmosphere;	98%

chloro(dimethylsulfide) gold(I) (29892-37-3) + 3-ethyl-4-(4-methylphenyl)-5-(2-methoxypyridin-5-yl)-1-propyl-3H-imidazolium hexafluorophosphate + lithium bromide (7550-35-8) → bromido[3-ethyl-4-(4-methylphenyl)-5-(2-methoxypyridin-5-yl)-1-propyl-1,3-dihydro-2H-imidazol-2-ylidene]gold(I)

Conditions	Yield
Stage #1: 3-ethyl-4-(4-methylphenyl)-5-(2-methoxypyridin-5-yl)-1-propyl-3H-imidazolium hexafluorophosphate With silver(l) oxide In methanol; dichloromethane at 20℃; Inert atmosphere; Darkness; Stage #2: chloro(dimethylsulfide) gold(I); lithium bromide In methanol; dichloromethane at 20℃; for 6h; Inert atmosphere; Darkness;	98%

(N,N'-dibutylbenzimidazolin-2-ylidene)gold(I) chloride + lithium bromide (7550-35-8) → (N,N'-dibutylbenzimidazolin-2-ylidene)gold(I) bromide

Conditions	Yield
In acetone Au complex and LiBr (10-fold excess) dissolved in acetone, mixt. stirredat ambient temp. for 24 h; evapn. under vac., residue dissolved in CH2Cl2, soln. dried over MgSO4, filtered, filtrate evapd. under vac., column chromy. (silica gel, CH2Cl2), evapn. under vac.;	97.6%

Pd((C5NH4)2C4N2H2)Cl2 (97226-52-3) + lithium bromide (7550-35-8) → Pd((C5NH4)2C4N2H2)Br2 (97226-54-5)

Conditions	Yield
In acetonitrile to suspn. of Pd(dppn)Cl2 in acetonitrile is added LiBr (molar ratio 1:1) and mixt. is stirred at room temp. for 10 days; ppt. is filtered, washed with water, ethanol, Et2O and dried under vac.; elem. anal.;	97%

(1,3-bis(tert-butyl)imidazol-2-ylidene)gold(I) chloride + lithium bromide (7550-35-8) → (1,3-bis(tert-butyl)imidazol-2-ylidene)gold(I) bromide

Conditions	Yield
In acetone soln. of Au carbene complex and LiBr in acetone was stirred for 16 h; solvent removed (vac.); residue dissolved (partially) in CH2Cl2; soln. passed through a short plug of silica; solvent evapd; elem. anal.;	97%
In acetone at 20℃; for 24h;	85%
In acetone byproducts: LiCl; stirring soln. of gold compd. and lithium bromide in acetone at room temp. for 24 h; evapn., addn. of CH2Cl2, drying over MgSO4, filtration over silica gel, concn., addn. of pentane, filtration, washing with cold pentane, drying,elem. anal.;	73%

[Ir(η5-C5Me5)(CO)(CF2CF3)I] + silver trifluoromethanesulfonate (2923-28-6) + lithium bromide (7550-35-8) → [iridium(III)(Cp*)(carbonyl)(perfluoroethyl)(bromide)] (1262658-90-1)

Conditions	Yield
In dichloromethane Schlenk technique, under N2; Ir complex (0.067 mmol) treated with Ag(OTf) (0.335 mmol) in CH2Cl2 soln. overnight, filtered, filtrate removed, treated with soln. of LiBr (0.192 mmol) for 1 h; solvent removed in vac., residue extracted with CH2Cl2, filtered, solvent removed under vac.; elem. anal.;	97%

C29H37IrOP2S2 + lithium bromide (7550-35-8) → C29H36BrIrP2S2

Conditions	Yield
In toluene at 20℃; for 1h;	97%

dihydrogen tetrachloropalladate(II) + lithium bromide (7550-35-8) + ruphos (787618-22-8) → [HRuPhos]2[Pd2Br6]

Conditions	Yield
Stage #1: dihydrogen tetrachloropalladate(II); ruphos In acetone at 18 - 27℃; for 0.5h; Stage #2: lithium bromide In water; acetone	97%

bis(1,5-cyclooctadiene)nickel (0) (1295-35-8) + 4-methoxy-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl triflate + lithium bromide (7550-35-8) + tricyclohexylphosphine (2622-14-2) → trans-bromo[4-methoxy-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl][bis(tricyclohexylphosphine)]nickel(II)

Conditions	Yield
In tetrahydrofuran at 20℃; for 2h; Inert atmosphere;	96.1%

[(η6-hexamethylbenzene)2Fe][PF6]2 + lithium bromide (7550-35-8) → bis(η6-hexamethyl(benzene))iron(II) bromide

Conditions	Yield
In acetone filtration, washing (acetone) ,drying (vac.); elem. anal.;	96%

[(C6H5(CH3)2P)ClPt((CH3)2NCH2CHCHCH2N(CH3)2)PtCl(P(CH3)2C6H5)] (82371-20-8) + lithium bromide (7550-35-8) → [(C6H5(CH3)2P)BrPt((CH3)2NCH2CHCHCH2N(CH3)2)PtBr(P(CH3)2C6H5)] (82371-22-0)

Conditions	Yield
In acetone educts refluxed together in acetone for 4 h; evapd. in vac., recrystd. from CH2Cl2-light petroleum; elem. anal.;	96%

[Re(CH3O)(OClO3)(CO)(NO)(P(C6H5)3)2]*H2O (98481-43-7) + lithium bromide (7550-35-8) → [ReBr(OCH3)(CO)(NO)(P(C6H5)3)2] (98481-45-9)

Conditions	Yield
In methanol; dichloromethane dissolving Re methoxide in CH2Cl2-methanol (1:1) under N2; heating soln. to reflux; addn. of LiBr;; dichloromethane removed under reduced pressure; pptn.;;	96%

Upstream product

• 554-13-2 lithium carbonate 
• 7726-95-6 bromine 
• 7439-93-2 lithium 
• 1112-48-7 triethyl-bromo-silane 
• 74-83-9 methyl bromide 
• 94527-62-5 tetralithium hexacosaphosphide*16THF 
• 17933-16-3 dibromomethylborane 
• 110-70-3 N,N`-dimethylethylenediamine 
• 111-74-0 N,N'-diethylethylenediamine 
• 91573-48-7 3-bromo-4,5-diethyl-1,2,3-dithiaborole 
• 920-39-8 isopropylmagnesium bromide 
• 4039-32-1 lithium hexamethyldisilazane 
• 7789-59-5 phosphorus(V) oxybromide 

Downstream Products

• 7726-95-6 bromine 
• 16397-91-4 manganese(II) 
• 13172-31-1 disulphur dibromide 
• 22518-41-8 {PtBr2} 
• 30134-05-5 C₂₄H₃₃Br₂MoOP₃, Chatt blue 
• 89655-06-1 mer-[Cr(bis(2-diphenylphosphinoethyl)phenylphosphine)Br₃] 
• 42536-25-4 WBr(CO)2(NO)(P(C₆H₅)3)2 
• 42536-24-3 WBr(CO)2(NO)(P(C₆H₅)3)2 
• 89655-07-2 Cr(CH₂P(C₆H₅)(CH₂CH₂P(C₆H₅)2))2Br₃ 
• 110412-96-9 [Pd(ClC₆H₃CHNC₆H₅)Br(P(C₂H₅)3)2] 

Relevant articles and documents

[GA16(PtBu2)10]: A gallium phosphide sheathed core of four naked Ga atoms?

Like inverse P4O10, a nearly tetrahedral Ga4P10 shell encloses a gallium-rich core with a distorted tetrahedral Ga4 center in the neutral metalloid cluster compound [Ga16(PtBu2)10].

Competitive interactions and glassy state extension in lithium salt solutions

We report measurements of high- and low-temperature limits of the liquid states of aqueous solutions for two common aqueous salt solutions. The liquid range extends from the glass transition temperature to the boiling point, and is maximized when the anion basicity is minimized. These limits and other characteristic temperatures have been determined by DTA and DSC studies of solution samples which are used to generate the most complete phase diagram yet available for the LiBr + H2O system. The glass-formation region has been extended by developing an emulsification technique suitable for use with concentrated aqueous salt solutions. Comparison of boiling points, liquidus temperatures, and glass transition temperatures shows that the reduction of the water content below 3H2O per Li+ is accompanied by important energetic effects. These are not present in the corresponding lithium acetate solutions, which exhibit relatively much lower boiling points. This is attributed to the stronger water - anion interaction in the lithium acetate system which is proportional to the anion basicity. Water activity increases and boiling points are lowered when the anions are more basic, but total cohesion, manifested by the glass transition temperature, increases. By contrast, addition of anion complexing salts such as ZnBr2 and ZnCl2 to LiBr-H2O solutions to reduce the anion basicity results in increased boiling points to over 200 ?°C as well as decreased crystallization temperatures. ? 1999 American Chemical Society.

In44 mit In4-Tetraeder und In4Se44 mit In4Se4-Heterocubanstruktur

The reaction of InIBr with LiC(SiMe3)3*2THF yields the In(I) alkyl In44 1 in 70percent yield. 1 was characterized by a crystal structure determination showing a nearly undistorted In4 tetrahedron with mean In-In distances of 300.2(1) pm.Reaction of 1 with elemental Se gives In4Se44 2 with a slightly distorted In4Se4 hetero cubane structure.Keywords: Indium; Tetrahedron; X-ray structure; Cluster; Selenium; Heterocubane

Synthesis, characterization, and catalytic behavior of methoxy- and dimethoxy-substituted pyridinium-type ionic liquids

Synthesis of methoxy-substituted pyridinium-type ionic liquids from a nontoxic and easy method is described. Catalytic behaviors of synthesized ionic liquids were investigated with various concentrations for the Mannich reaction. We have observed that methoxy- and dimethoxy-substituted pyridinium bromides showed better catalytic behavior than other ionic liquids.

PROCESS FOR THE RECOVERY OF MATERIALS FROM A DESULFURIZATION REACTION

Disclosed herein is an improved method for regenerating materials from a desulfurization/demetallation reaction. The desulfurization/demetallation reaction preferably has products including one or more of an alkali sulfide, polysulfide or hydrosulfide, or alkali earth sulfide, polysulfide, or hydrosulfide. The method includes the steps of reacting the desulfurization/demetallation products with a halogen, liberating and removing sulfur from the product, and then electrolyzing the halogenated products to separate the halogen from the alkali metal or alkali earth metal.