METHYL 3-(4-CHLOROPHENYL)-2-METHOXYCARBONYL-4-NITROBUTANOATE

Base Information

Chemical Name:METHYL 3-(4-CHLOROPHENYL)-2-METHOXYCARBONYL-4-NITROBUTANOATE
CAS No.:360072-54-4
Molecular Formula:C13H14ClNO6
Molecular Weight:315.71
Hs Code.:2917399090
Mol file:360072-54-4.mol

Synonyms:methyl 3-(4-chlorophenyl)-2-methoxycarbonyl-4-nitrobutanoate;3,3-dimethoxycarbonyl-1-nitro-2-(4-chlorophenyl)propane;methyl 2-carbomethoxy-4-nitro-3-(4-chlorophenyl)butyrate;methyl 2-carbomethoxy-4-nitro-3-(4-bromophenyl)butyrate;dimethyl [(1R)-1-(4-bromophenyl)-2-nitroethyl]propanedioate;dimethyl [(1S)-1-(4-bromophenyl)-2-nitroethyl]propanedioate;Propanedioic acid,[1-(4-bromophenyl)-2-nitroethyl]-,dimethyl ester;

Suppliers and Price of METHYL 3-(4-CHLOROPHENYL)-2-METHOXYCARBONYL-4-NITROBUTANOATE

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
METHYL 3-(4-CHLOROPHENYL)-2-METHOXYCARBONYL-4-NITROBUTANOATE 95.00%
5MG
$ 502.16

Total 3 raw suppliers

Chemical Property of METHYL 3-(4-CHLOROPHENYL)-2-METHOXYCARBONYL-4-NITROBUTANOATE

Chemical Property:

Vapor Pressure:7.9E-08mmHg at 25°C
Boiling Point:436.7oC at 760 mmHg
Flash Point:217.9oC
PSA：98.42000
Density:1.328g/cm3
LogP:2.18570

Purity/Quality:

97% ^*data from raw suppliers

METHYL 3-(4-CHLOROPHENYL)-2-METHOXYCARBONYL-4-NITROBUTANOATE 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

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Technology Process of METHYL 3-(4-CHLOROPHENYL)-2-METHOXYCARBONYL-4-NITROBUTANOATE

There total 7 articles about METHYL 3-(4-CHLOROPHENYL)-2-METHOXYCARBONYL-4-NITROBUTANOATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 706-07-0,5153-70-8
1-chloro-4-(2-nitrovinyl)benzene

: 108-59-8
malonic acid dimethyl ester

: 360072-54-4
methyl 2-carbomethoxy-4-nitro-3-(4-chloro-phenyl)-butyrate

Guidance literature:: With C₂₃H₃₇N₃O₉S; In toluene; at -20 ℃; for 20h; enantioselective reaction;
DOI:10.1055/s-0028-1087370

Reference yield: 96.0%

: 101671-01-6,5153-70-8
1-nitro-2-(4-chlorophenyl)ethylene

: 108-59-8
malonic acid dimethyl ester

: 360072-54-4
methyl 2-carbomethoxy-4-nitro-3-(4-chloro-phenyl)-butyrate

Guidance literature:: With triethylamine; at 20 ℃; Green chemistry;

Reference yield: 75.0%

: 75-52-5
nitromethane

: 104-88-1
4-chlorobenzaldehyde

: 108-59-8
malonic acid dimethyl ester

: 360072-54-4
methyl 2-carbomethoxy-4-nitro-3-(4-chloro-phenyl)-butyrate

Guidance literature:: With aminopropyl-silica-based catalyst; dimethylaminopropyl-silica-based solid; In o-xylene; at 70 ℃; for 18h; Green chemistry;
DOI:10.1002/anie.201403049