13,15-dideoxyaconitine

Base Information

• Chemical Name: 13,15-dideoxyaconitine
• CAS No.: 77757-14-3
• Molecular Formula: C₃₄H₄₇NO₉
• Molecular Weight: 613.748
• Mol file: 77757-14-3.mol

Synonyms:11aH-12,3,6a-Ethanylylidene-7,9-methanonaphth[2,3-b]azocine,aconitane-3,8,14-triol deriv.; 13,15-Dideoxyaconitine;13-Dehydroxyindaconitine; 3-Hydroxychasmanine 8-acetate 14-benzoate;8-Acetyl-14-benzoylezochasmanine; Ezochasmanine 8-acetate 14-benzoate

Chemical Property of 13,15-dideoxyaconitine

Chemical Property:

• Vapor Pressure: 7.49E-16mmHg at 25°C
• Boiling Point: 631.4°C at 760 mmHg
• Flash Point: 335.7°C
• Density: 1.25g/cm³

Purity/Quality:

HPLC≥95% ^*data from raw suppliers

13-Dehydroxyindaconintine ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 13,15-dideoxyaconitine

There total 5 articles about 13,15-dideoxyaconitine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C37H48Cl3NO11 → 8-acetyl-14-benzoylezochasmanine (77757-14-3)

Guidance literature:

With acetic acid; zinc; for 5h; Ambient temperature;

Reference yield:

benzoyl chloride (98-88-4) → 8-acetyl-14-benzoylezochasmanine (77757-14-3)

Guidance literature:

Multi-step reaction with 4 steps

1: 68 percent / pyridine / 2 h / -18 °C

2: 83 percent / pyridine

3: p-TsOH / 2 h / 85 - 92 °C

4: Zn, HOAc / 5 h / Ambient temperature

With pyridine; toluene-4-sulfonic acid; acetic acid; zinc;

Reference yield:

ezochasmanine → 8-acetyl-14-benzoylezochasmanine (77757-14-3)

Guidance literature:

Multi-step reaction with 4 steps

1: 68 percent / pyridine / 2 h / -18 °C

2: 83 percent / pyridine

3: p-TsOH / 2 h / 85 - 92 °C

4: Zn, HOAc / 5 h / Ambient temperature

With pyridine; toluene-4-sulfonic acid; acetic acid; zinc;

upstream raw materials:

benzoyl chloride

Refernces