(Z)-Dodeca-9,11-dienyl acetate

Base Information

• Chemical Name: (Z)-Dodeca-9,11-dienyl acetate
• CAS No.: 51760-35-1
• Molecular Formula: C14H24 O2
• Molecular Weight: 224.343
• Hs Code.: 2915390090
• European Community (EC) Number: 257-387-6
• DSSTox Substance ID: DTXSID601309966
• Nikkaji Number: J698J
• Wikidata: Q76305351
• Metabolomics Workbench ID: 3891
• Mol file: 51760-35-1.mol

Synonyms:(Z)-Dodeca-9,11-dienyl acetate;9Z,11-Dodecadienyl acetate;51760-35-1;EINECS 257-387-6;Z-9,11-Dodecadien-1-ol acetate;z-9,11-dodecadienyl acetate;SCHEMBL832297;(Z)-9,11-dodecadienyl acetate;ARPQLVHCERGNAB-PLNGDYQASA-N;DTXSID601309966;LMFA07010246;(9Z)-9,11-Dodecadienyl acetate #;(Z)-9,11-Dodecadien-1-ol acetate;9,11-Dodecadien-1-ol, acetate, (Z)-

Chemical Property of (Z)-Dodeca-9,11-dienyl acetate

Chemical Property:

• Vapor Pressure: 0.000745mmHg at 25°C
• Boiling Point: 307°C at 760 mmHg
• Flash Point: 104.1°C
• PSA: 26.30000
• Density: 0.89g/cm³
• LogP: 4.02240
• XLogP3: 4.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 11
• Exact Mass: 224.177630004
• Heavy Atom Count: 16
• Complexity: 207

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=O)OCCCCCCCCC=CC=C
• Isomeric SMILES: CC(=O)OCCCCCCCC/C=C\C=C

Technology Process of (Z)-Dodeca-9,11-dienyl acetate

There total 41 articles about (Z)-Dodeca-9,11-dienyl acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.1%

acetic anhydride (108-24-7) + (Z)-9,11-dodecadienol (61618-05-1) → (Z)-9,11-dodecadienyl acetate (51760-35-1)

Guidance literature:

With pyridine; In benzene; at 20 ℃; for 6h; Cooling with ice;

Reference yield: 94.0%

Acetic acid (9S,10R)-9-hydroxy-10-trimethylsilanyl-dodec-11-enyl ester (79309-72-1) → (Z)-9,11-dodecadienyl acetate (51760-35-1)

Guidance literature:

With potassium hydride; In tetrahydrofuran; for 0.166667h;

DOI:10.1016/S0040-4039(01)90542-8

Reference yield: 77.0%

12-acetoxy-4-hydroxy-3-phenylseleno-1-dodecene (85363-39-9) → (E)-9,11-dodecadien-1-yl acetate (50767-78-7) + (Z)-9,11-dodecadienyl acetate (51760-35-1)

Guidance literature:

With toluene-4-sulfonic acid; In pentane; for 7h; Yields of byproduct given; Heating;

DOI:10.1021/jo00180a027

upstream raw materials:

9-acetoxynonal

allyltriphenylphosphonium bromide

1-iodo, (Z)1-decen, 10-yl acetate

vinylmagnesium chloride