Vinylmagnesium chloride

Base Information

• Chemical Name: Vinylmagnesium chloride
• CAS No.: 3536-96-7
• Molecular Formula: C2H3ClMg
• Molecular Weight: 86.8038
• Hs Code.: 29319090
• Mol file: 3536-96-7.mol

Synonyms:Magnesium,chlorovinyl- (7CI,8CI);Vinylmagnesium chloride (6CI);Chloroethenylmagnesium;Ethenylmagnesium chloride;

Chemical Property of Vinylmagnesium chloride

Chemical Property:

• Appearance/Colour: dark brown solution
• Boiling Point: 66 °C
• Flash Point: ?1°F
• PSA: 0.00000
• Density: 0.980g/mLat 20°C
• LogP: 1.36870
• Storage Temp.: 0-6°C
• Water Solubility.: vigorous reaction

Purity/Quality:

Purity greater than 99.5% ^*data from raw suppliers

Vinylmagnesium chloride solution 1.6 M in THF ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F,C
• Hazard Codes: F,C
• Statements: 11-14/15-19-22-34-40-37
• Safety Statements: 16-26-36/37/39-43-45-7/8-43B-30

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Uses: Grignard reagent. Vinylmagnesium chloride (Grignard reagent) can be prepared from vinyl chloride and then used to make a variety of useful end products or intermediates by adding a vinyl anion to organic functional groups. For instance, the vinylmagnesium compounds can be coupled with cuprous chloride, CuCl, at ?60 °C (?76 °F) to give 1,3-butadiene, while vinyl ketones and alcohols can be prepared by the addition of vinylmagnesium chloride to organic acids. Used with iron pentadienoate complexes in a synthesis of divinyl cyclopropanes.

Technology Process of Vinylmagnesium chloride

There total 3 articles about Vinylmagnesium chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

chloroethylene (75-01-4,9002-86-2) → vinylmagnesium chloride (3536-96-7)

Guidance literature:

With magnesium; In tetrahydrofuran;

Reference yield:

chloroethylene (75-01-4,9002-86-2) + magnesium (7439-95-4) → vinylmagnesium chloride (3536-96-7)

Guidance literature:

In tetrahydrofuran;

Reference yield:

→ vinylmagnesium chloride (3536-96-7)

Guidance literature:

upstream raw materials:

chloroethylene

magnesium

Downstream raw materials:

homoalylic alcohol

allyl alcohol

4-penten-3-one

triphenyl-vinyl stannane

Refernces

• 1、 -. "ROSUVASTATIN CALCIUM INTERMEDIATE AND METHOD FOR PREPARING THE SAME". Page/Page column 3-4. . Retrieved 2012/12/14.
• 2、 Zhun. "Side products in the syntheses of vinylsilanes and vinylsiloxanes using vinylmagnesium chloride". . p. 1746 - 1748. Retrieved 2007/10/03.