Methyl 3,3-dimethylcyclobut-1-ene-1-carboxylate

Base Information

Chemical Name:Methyl 3,3-dimethylcyclobut-1-ene-1-carboxylate
CAS No.:37676-91-8
Molecular Formula:C8H12O2
Molecular Weight:140.18000
Hs Code.:2916209090
DSSTox Substance ID:DTXSID00545547
Nikkaji Number:J1.619.596K
Wikidata:Q82423077
Mol file:37676-91-8.mol

Synonyms:37676-91-8;Methyl 3,3-dimethylcyclobut-1-ene-1-carboxylate;methyl 3,3-dimethylcyclobutene-1-carboxylate;1-Cyclobutene-1-carboxylic acid, 3,3-dimethyl-, methyl ester;methyl (3,3-dimethyl-1-cyclobutene)carboxylate;DTXSID00545547;PB19669;CS-0183546;Methyl3,3-dimethylcyclobut-1-ene-1-carboxylate;P12476;EN300-1697686;3,3-Dimethyl-cyclobut-1-enecarboxylic acid methyl ester

Suppliers and Price of Methyl 3,3-dimethylcyclobut-1-ene-1-carboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Synthonix
Methyl3,3-dimethylcyclobut-1-ene-1-carboxylate 95+%
5g
$ 1420.00

Matrix Scientific
Methyl3,3-dimethylcyclobut-1-ene-1-carboxylate 95+%
1g
$ 826.00

Crysdot
Methyl3,3-dimethylcyclobut-1-ene-1-carboxylate 95+%
5g
$ 1557.00

Crysdot
Methyl3,3-dimethylcyclobut-1-ene-1-carboxylate 95+%
1g
$ 518.00

Total 6 raw suppliers

Chemical Property of Methyl 3,3-dimethylcyclobut-1-ene-1-carboxylate

Chemical Property:

Boiling Point:52 °C(Press: 14 Torr)
PSA：26.30000
Density:1.013±0.06 g/cm3(Predicted)
LogP:1.51570
XLogP3:1.8
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:2
Exact Mass:140.083729621
Heavy Atom Count:10
Complexity:189

Purity/Quality:

97% ^*data from raw suppliers

Methyl3,3-dimethylcyclobut-1-ene-1-carboxylate 95+% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC1(CC(=C1)C(=O)OC)C

Technology Process of Methyl 3,3-dimethylcyclobut-1-ene-1-carboxylate

There total 5 articles about Methyl 3,3-dimethylcyclobut-1-ene-1-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

: 108965-04-4
N-(1-carbomethoxy-3,3-dimethyl-2-cyclobutyl) N-methyl pyrrolidinium iodide

: 37676-91-8
methyl (3,3-dimethyl-1-cyclobutene)carboxylate

Guidance literature:: With sodium methylate; In methanol; for 1h;
DOI:10.1016/S0040-4020(01)87383-X

Reference yield:

: N-(1-methoxycarbonyl-3,3-dimethyl-2-cyclobutyl)-N,N,N-trimethylamonnium iodide

: 37676-91-8
methyl (3,3-dimethyl-1-cyclobutene)carboxylate

: methyl 3,3-dimethyl-2-methoxycyclobutane-1-carboxylate

Guidance literature:: With sodium hydride; In tetrahydrofuran; at 20 ℃; Title compound not separated from byproducts;
DOI:10.1021/ma010683i

Reference yield:

: 73330-88-8
methyl 3,3-dimethyl-2-(1-pyrrolidinyl)-cyclobutanecarboxylate

: 37676-91-8
methyl (3,3-dimethyl-1-cyclobutene)carboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: 90 percent / diethyl ether / 336 h / Ambient temperature

2: 63 percent / sodium methoxide / methanol / 1 h

With sodium methylate; In methanol; diethyl ether;
DOI:10.1016/S0040-4020(01)87383-X