Benzene, [(1E,3S,4R,5S,6S,7E)-8-iodo-3,5-dimethoxy-4,6-dimethyl-1,7-octadien yl]-

Base Information

Chemical Name:Benzene, [(1E,3S,4R,5S,6S,7E)-8-iodo-3,5-dimethoxy-4,6-dimethyl-1,7-octadien yl]-
CAS No.:387821-97-8
Molecular Formula:C18H25IO2
Molecular Weight:400.3
Hs Code.:

Synonyms:

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Chemical Property of Benzene, [(1E,3S,4R,5S,6S,7E)-8-iodo-3,5-dimethoxy-4,6-dimethyl-1,7-octadien yl]-

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Technology Process of Benzene, [(1E,3S,4R,5S,6S,7E)-8-iodo-3,5-dimethoxy-4,6-dimethyl-1,7-octadien yl]-

There total 4 articles about Benzene, [(1E,3S,4R,5S,6S,7E)-8-iodo-3,5-dimethoxy-4,6-dimethyl-1,7-octadien yl]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 75-47-8
iodoform

: 329362-90-5
(2R,3R,4R,5S,E)-3,5-dimethoxy-2,4-dimethyl-7-phenylhept-6-enal

: 387821-97-8
1-((1E,3S,4R,5S,6S,7E)-8-iodo-3,5-dimethoxy-4,6-dimethylocta-1,7-dienyl)benzene

Guidance literature:: With chromium dichloride; In tetrahydrofuran; at 20 ℃; for 0.5h; optical yield given as %de; diastereoselective reaction; Inert atmosphere; Darkness;
DOI:10.1021/jo301210f

Reference yield:

: 307492-71-3
3,5-dimethoxy-2,4-dimethyl-7-phenyl-(2S,3S,4R,5S,6E)-6-hepten-1-ol

: 387821-97-8
1-((1E,3S,4R,5S,6S,7E)-8-iodo-3,5-dimethoxy-4,6-dimethylocta-1,7-dienyl)benzene

Guidance literature:: Multi-step reaction with 2 steps

1: Dess-Martin periodinane / CH₂Cl₂ / 0.25 h / 20 °C

2: 39.6 mg / CrCl₂ / tetrahydrofuran / 1 h / 20 °C

With chromium dichloride; Dess-Martin periodane; In tetrahydrofuran; dichloromethane; 1: Dess-Martin oxidation;
DOI:10.1021/jo047732k

Reference yield:

: 307492-70-2
tert-butyl((2S,3S,4R,5S,E)-3,5-dimethoxy-2,4-dimethyl-7-phenylhept-6-enyloxy)diphenylsilane

: 387821-97-8
1-((1E,3S,4R,5S,6S,7E)-8-iodo-3,5-dimethoxy-4,6-dimethylocta-1,7-dienyl)benzene

Guidance literature:: Multi-step reaction with 3 steps

1: 99 percent / TBAF / tetrahydrofuran / 16 h / 25 °C

2: Dess-Martin periodinane / CH₂Cl₂ / 0.25 h / 20 °C

3: 39.6 mg / CrCl₂ / tetrahydrofuran / 1 h / 20 °C

With chromium dichloride; tetrabutyl ammonium fluoride; Dess-Martin periodane; In tetrahydrofuran; dichloromethane; 2: Dess-Martin oxidation;
DOI:10.1021/jo047732k