Benzene, [(6-bromo-1-cyclohexen-1-yl)sulfonyl]-

Base Information

Chemical Name:Benzene, [(6-bromo-1-cyclohexen-1-yl)sulfonyl]-
CAS No.:396728-95-3
Molecular Formula:C12H13BrO2S
Molecular Weight:301.204
Hs Code.:
DSSTox Substance ID:DTXSID60461390

Synonyms:396728-95-3;Benzene, [(6-bromo-1-cyclohexen-1-yl)sulfonyl]-;DTXSID60461390

Suppliers and Price of Benzene, [(6-bromo-1-cyclohexen-1-yl)sulfonyl]-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Benzene, [(6-bromo-1-cyclohexen-1-yl)sulfonyl]-

Chemical Property:

XLogP3:2.9
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:2
Exact Mass:299.98196
Heavy Atom Count:16
Complexity:361

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1CC=C(C(C1)Br)S(=O)(=O)C2=CC=CC=C2

Technology Process of Benzene, [(6-bromo-1-cyclohexen-1-yl)sulfonyl]-

There total 6 articles about Benzene, [(6-bromo-1-cyclohexen-1-yl)sulfonyl]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 85894-93-5
6-bromo-1-(phenylthio)cyclohexene

: 396728-95-3
1-(phenylsulfonyl)-6-bromocyclohexene

Guidance literature:: With Oxone; In tetrahydrofuran; water; isopropyl alcohol; at 0 - 20 ℃;
DOI:10.1021/jo0107047

Reference yield:

: 4922-47-8
1-(phenylthio)cyclohex-1-ene

: 396728-95-3
1-(phenylsulfonyl)-6-bromocyclohexene

Guidance literature:: Multi-step reaction with 2 steps

1: Na₂WO₄; aq. H₃PO₄; NaBr / PhPO(OH)2; H₂O₂

2: Na₂WO₄; aq. H₂O₂; PhPO(OH)2 / tricaprylylmethylammonium hydrogensulfate / toluene / 3 h / 25 °C

With sodium tungstate; phosphoric acid; phenylphosphonate; dihydrogen peroxide; sodium bromide; phenylphosphonate; dihydrogen peroxide; methyl tri-n-octyl ammonium hydrogen sulfate; In toluene;
DOI:10.1055/s-2004-822318

Reference yield:

: 108-98-5
thiophenol

: 396728-95-3
1-(phenylsulfonyl)-6-bromocyclohexene

Guidance literature:: Multi-step reaction with 3 steps

1: Montmorillonite KSF / toluene / 24 h / Heating

2: Na₂WO₄; aq. H₃PO₄; NaBr / PhPO(OH)2; H₂O₂

3: Na₂WO₄; aq. H₂O₂; PhPO(OH)2 / tricaprylylmethylammonium hydrogensulfate / toluene / 3 h / 25 °C

With sodium tungstate; Montmorillonite KSF; phosphoric acid; phenylphosphonate; dihydrogen peroxide; sodium bromide; phenylphosphonate; dihydrogen peroxide; methyl tri-n-octyl ammonium hydrogen sulfate; In toluene; 1: Dean-Stark condensation;
DOI:10.1055/s-2004-822318