Dichlorobis(triphenylphosphine)palladium

Base Information

• Chemical Name: Dichlorobis(triphenylphosphine)palladium
• CAS No.: 13965-03-2
• Molecular Formula: C36H30Cl2P2Pd
• Molecular Weight: 701.908
• Hs Code.: 28439090
• European Community (EC) Number: 237-744-2,233-495-9
• NSC Number: 122924
• Wikipedia: Bis(triphenylphosphine)palladium_chloride
• Mol file: 13965-03-2.mol

Synonyms:bis(triphenylphosphino)palladium dichloride;Bis(triphenylphosphine)dichloropalladium;Dichlorobis(triphenylphosphine)palladium;Bis(triphenylphosphine)palladium(II) dichloride;C36H30Cl2P2Pd;13965-03-2;C36-H30-Cl2-P2-Pd;bis(triphenylphosphine]palladium (II) chloride;Bis(Triphenylphosphine)palladium (II) chloride;Bis(triphenylphosphine)palladium chloride;bis(triphenylphosphine)palladium(ii)chloride;bis(triphenylphosphine)palladium(ii) chloride;bis(triphenylphosphine)palladium(ii)dichloride;Palladium(II)bis(triphenylphosphine) dichloride;bis(triphenylphosphine) palladiuml(ii) dichloride;BIS(TRIPHENYLPHOSPHINE)DICHLOROPALLADIUM(II);TRANS-BIS(TRIPHENYLPHOSPHINE)PALLADIUM(II)CHLORIDE;pdcl2(tpp)2;(Ph3P)2PdCl2;(PPh3)2PdCl2;Pd(Ph3P)2Cl2;(Ph3P)2 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Chemical Property of Dichlorobis(triphenylphosphine)palladium

Chemical Property:

• Appearance/Colour: Yellow crystalline powder
• Vapor Pressure: 0Pa at 25℃
• Melting Point: 260 °C
• Boiling Point: 360 °C at 760 mmHg
• Flash Point: 181.7 °C
• PSA: 27.18000
• LogP: 8.26860
• Storage Temp.: Store below +30°C.
• Sensitive.: Hygroscopic
• Solubility.: Chloroform (Slightly), Dichloromethane (Slightly, Heated), Methanol (Slightly,
• Water Solubility.: Insoluble in water. Soluble in benzene, and toluene.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 6
• Exact Mass: 702.03911
• Heavy Atom Count: 41
• Complexity: 490

Purity/Quality:

99% ^*data from raw suppliers

Dichlorobis(triphenylphosphine)Palladium(II) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn
• Hazard Codes: Xn
• Statements: 36/37/38-22-40-19
• Safety Statements: 37/39-26-36/37

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1=CC=C(C=C1)[PH+](C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)[PH+](C2=CC=CC=C2)C3=CC=CC=C3.Cl[Pd]Cl
• Uses: Bis(triphenylphosphine)palladium(II) chloride is used primarily in organometallic catalytic reactions due to the palladium content of the compound. It is also involved in crystalized structures of me tallacyclic complexes which show antiinflammatory and antifungal properties.

Technology Process of Dichlorobis(triphenylphosphine)palladium

There total 141 articles about Dichlorobis(triphenylphosphine)palladium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

hydrogenchloride (7647-01-0,15364-23-5) + palladium (7440-05-3) + triphenylphosphine (603-35-0) → bis-triphenylphosphine-palladium(II) chloride (13965-03-2)

Guidance literature:

hydrogenchloride; palladium; With aqua regia; at 80 ℃;

triphenylphosphine; In ethanol; at 70 ℃;

In ethanol; at 70 ℃; for 1h; Temperature; Solvent;

Reference yield: 95.0%

bis(benzonitrile)palladium(II) dichloride (15617-18-2,39958-10-6,14220-64-5) → bis-triphenylphosphine-palladium(II) chloride (13965-03-2)

Guidance literature:

With triphenylphosphine; In chloroform; isolation by filtration;

DOI:10.1021/ja00211a020

Reference yield: 95.0%

dihydrogen decachloro decaborate + palladium dichloride → bis-triphenylphosphine-palladium(II) chloride (13965-03-2) + [(Ph3P)4Pd2Cl2]closo-B10Cl10

Guidance literature:

With PPh₃; In ethanol; water; molar ratio borane:Pd:PPh3=1:2:4, 70°C, 2 h (pptn.); filtration, washing (H2O, EtOH, ether); extn. of PdCl2(PPh3)2 (toluene);elem. anal.;

upstream raw materials:

triphenylphosphine

trans-[Pd(triphenylphosphine)2(N₄CPh)2]

benzoyl chloride

tetrachloropalladium anion

Downstream raw materials:

N-(tert-butoxycarbonyl)4-(2-thiazolyl)-L-phenylalanine methyl ester

bis(triphenylphosphine)palladium dibromide

tetrakis(triphenylphosphine) palladium⁽⁰⁾

[Me₃SiN=PPh₂)2C=GeCl₂]

Refernces

• 1、 Lopez, Conception,Granell, Jaume. "Influences of the electronic and steric effects of the substituents in cyclopalladation of ferrocenylhydrazones". . p. 211 - 225. Retrieved 1998.
• 2、 Fairlamb, Ian J. S.,O'Brien, Ciara T.,Lin, Zhenyang,Lam, King Chung. "Regioselectivity in the Sonogashira coupling of 4,6-dichloro-2-pyrone". . p. 1213 - 1216. Retrieved 2006.
• 3、 Cheng, Peng,Gao, Jianbo,Ma, Jian-Gong,Zhou, Zhenzhen. "Quasi-homogeneous catalytic conversion of CO2into quinazolinones inside a metal-organic framework microreactor". . p. 5456 - 5460. Retrieved 2021.
• 4、 de León, Antonio,Pons, Josefina,García-Antón, Jordi,Solans, Xavier,Font-Bardía, Mercè,Ros, Josep. "Reactivity of [PdCl(bdtp)](BF4) with monodentate neutral and anionic ligands. Structure of [Pd(bdtp)(PPh3)](BF4)2 (bdtp = 1,5-bis(3,5-dimethyl-1-pyrazolyl)-3-thiapentane)". . p. 3801 - 3806. Retrieved 2009.
• 5、 Giannoccaro, Potenzo,Dibenedetto, Angela,Gargano, Michele,Quaranta, Eugenio,Aresta, Michele. "Interaction of palladium(II) complexes with amino-alcohols: Synthesis of new amino-carbonyl complexes, key intermediates to cyclic carbamates". . p. 967 - 975. Retrieved 2008.
• 6、 Funk, Jeffrey K.,Newsham, David K.,Goldstein, David N.,Liu, Shengsheng,Sen, Ayusman. "Catalytic carbonylation of 4-penten-1-ol to ε-caprolactone and oligocaprolactone". . p. 185 - 192. Retrieved 2005.
• 7、 Qin, Guiping,Li, Lixin,Li, Jiawen,Huang, Hanmin. "Palladium-Catalyzed Formal Insertion of Carbenoids into Aminals via C-N Bond Activation". . p. 12490 - 12493. Retrieved 2015.
• 8、 Mason, Mark R.,Verkade, John G.. "Fluoride-assisted reduction of palladium(II) phosphine complexes". . p. 864 - 865. Retrieved 1990.
• 9、 Davies, Clive,Kilner, Melvyn. "". . p. 403 - 414. Retrieved 1992.
• 10、 Jin, Young-Jae,Kawamura, Yuto,Teraguchi, Masahiro,Aoki, Toshiki,Kwak, Giseop. "Thermodynamically stable, highly emissive poly(diphenylacetylene) derivative containing long alkyl side chain without silylene linkage". . p. 81 - 86. Retrieved 2017.