2-dioxaborolan-2-yl)quinolin-2(1H)-one

Base Information

Chemical Name:2-dioxaborolan-2-yl)quinolin-2(1H)-one
CAS No.:400620-72-6
Molecular Formula:C15H20BNO3
Molecular Weight:273.14
Hs Code.:2934999090
Mol file:400620-72-6.mol

Synonyms:N-Boc-1,2,3,4-tetrahydroisoquinoline-6-boronicacidpinacolester;6-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-3,4-dihydro-1H-isoquinoline-2-carboxylic acid tert-butylester;1,1-dimethylethyl 6-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-3,4-dihydro-2(1H)-isoquinolinecarboxylate;TERT-BUTYL 6-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)-3,4-DIHYDROISOQUINOLINE-2(1H)-CARBOXYLATE;6-(tetramethyl-1,3,2-dioxaborolan-2-yl)-1,2,3,4-ntetrahydroquinolin-2-one;6-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-3,4-dihydroquinolin-2(1H)-one;6-(4,4,5,5-Tetramethyl-[1,3,2]dioxaborolan-2-yl)3,4-dihydro-1H-quinolin-2-one;

Suppliers and Price of 2-dioxaborolan-2-yl)quinolin-2(1H)-one

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Crysdot
6-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)-3,4-dihydroquinolin-2(1H)-one 95+%
1g
$ 725.00

Crysdot
6-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)-3,4-dihydroquinolin-2(1H)-one 95+%
5g
$ 2178.00

ChemScene
(2-OXO-1,2,3,4-TETRAHYDROQUINOLIN-6-YL)BORONICACIDPINACOLESTER ≥97.0%
5g
$ 1452.00

ChemScene
(2-OXO-1,2,3,4-TETRAHYDROQUINOLIN-6-YL)BORONICACIDPINACOLESTER ≥97.0%
1g
$ 395.00

ChemScene
(2-OXO-1,2,3,4-TETRAHYDROQUINOLIN-6-YL)BORONICACIDPINACOLESTER ≥97.0%
250mg
$ 165.00

ChemScene
(2-OXO-1,2,3,4-TETRAHYDROQUINOLIN-6-YL)BORONICACIDPINACOLESTER ≥97.0%
100mg
$ 175.00

American Custom Chemicals Corporation
6-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)-3,4-DIHYDROQUINOLIN-2-(1H)ONE 95.00%
1G
$ 937.65

American Custom Chemicals Corporation
6-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)-3,4-DIHYDROQUINOLIN-2-(1H)ONE 95.00%
5MG
$ 497.20

Ambeed
6-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)-3,4-dihydroquinolin-2(1H)-one 98+%
250mg
$ 167.00

Ambeed
6-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)-3,4-dihydroquinolin-2(1H)-one 98+%
100mg
$ 112.00

Total 12 raw suppliers

Chemical Property of 2-dioxaborolan-2-yl)quinolin-2(1H)-one

Chemical Property:

Boiling Point:445.1±45.0 °C(Predicted)
PKA:14.90±0.20(Predicted)
PSA：47.56000
Density:1.14±0.1 g/cm3(Predicted)
LogP:2.00850
Storage Temp.:2-8°C

Purity/Quality:

97% ^*data from raw suppliers

6-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)-3,4-dihydroquinolin-2(1H)-one 95+% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 2-dioxaborolan-2-yl)quinolin-2(1H)-one

There total 2 articles about 2-dioxaborolan-2-yl)quinolin-2(1H)-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: C₂₁H₁₆NOS₂⁽¹⁺⁾*CF₃O₃S^(1-)

: 73183-34-3
bis(pinacol)diborane

: 400620-72-6
6-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-3,4-dihydroquinolin-2(1H)-one

: 92-85-3
Thianthrene

Guidance literature:: With palladium diacetate; sodium pivalate; XPhos; In dichloromethane; acetone; at 20 ℃; for 21h; Inert atmosphere;
DOI:10.1002/cjoc.202000212

Reference yield:

: 553-03-7
3,4-dihydro-2(1H)-quinolone

: 2362-50-7
thianthrene-5-oxide

: 400620-72-6
6-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-3,4-dihydroquinolin-2(1H)-one

: 92-85-3
Thianthrene

Guidance literature:: Multi-step reaction with 2 steps

1: dichloromethane / 1.5 h / -40 - 20 °C / Schlenk technique; Inert atmosphere

2: palladium diacetate; XPhos; sodium pivalate / acetone; dichloromethane / 21 h / 20 °C / Inert atmosphere

With palladium diacetate; sodium pivalate; XPhos; In dichloromethane; acetone;
DOI:10.1002/cjoc.202000212

Reference yield: 80.0%

: 400620-72-6
6-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-3,4-dihydroquinolin-2(1H)-one

: 349-03-1
1-bromo-4-trifluoromethyl-2-nitrobenzene

: 1232100-44-5
6-(2-nitro-4-trifluoromethylphenyl)-3,4-dihydroquinolin-2(1H)-one

Guidance literature:: With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium carbonate; In 1,4-dioxane; at 90 ℃; for 24h; Inert atmosphere;
DOI:10.1021/jm200448n