Verrucarin A, primary allylic alcohol OF

Base Information

Chemical Name:Verrucarin A, primary allylic alcohol OF
CAS No.:74516-64-6
Molecular Formula:C₂₇H₃₄O₁₀
Molecular Weight:518.561
Hs Code.:
NSC Number:317910
Mol file:74516-64-6.mol

Synonyms:16-hydroxyverrucarin A

Suppliers and Price of Verrucarin A, primary allylic alcohol OF

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
16-HYDROXY VERRUCARIN A 95.00%
5MG
$ 496.89

Total 7 raw suppliers

Chemical Property of Verrucarin A, primary allylic alcohol OF

Chemical Property:

Boiling Point:798.4oC at 760 mmHg
Flash Point:267.4oC
PSA：141.12000
Density:1.37g/cm3
LogP:1.14300
XLogP3:1.1
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:10
Rotatable Bond Count:1
Exact Mass:518.21519728
Heavy Atom Count:37
Complexity:1050

Purity/Quality:

99% ^*data from raw suppliers

16-HYDROXY VERRUCARIN A 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1CCOC(=O)C=CC=CC(=O)OC2CC3C4(C2(C5(CCC(=CC5O3)CO)COC(=O)C1O)C)CO4
Isomeric SMILES:CC1CCOC(=O)/C=C/C=C/C(=O)OC2CC3C4(C2(C5(CCC(=CC5O3)CO)COC(=O)C1O)C)CO4

Technology Process of Verrucarin A, primary allylic alcohol OF

There total 1 articles about Verrucarin A, primary allylic alcohol OF which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 48.0%

: 3148-09-2
verrucarin A

: 74516-64-6
16-hydroxyverrucarin A

: 74608-63-2
8β-hydroxyverrucarin A

Guidance literature:: With selenium(IV) oxide; acetic anhydride; acetic acid; at 100 ℃; for 0.75h;
DOI:10.1021/jm00183a018

Reference yield: 47.0%

: 74516-64-6
16-hydroxyverrucarin A

: 87532-32-9
16-hydroxy-9β,10β-epoxyverrucarin A

Guidance literature:: With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; Ambient temperature;
DOI:10.1021/jm00368a025

Reference yield:

: 74516-64-6
16-hydroxyverrucarin A

: 74516-69-1
4β,8α,15-trihydroxy-12,13-epoxytrichothecene

Guidance literature:: Multi-step reaction with 3 steps

1: 63 percent / CrO₃, pyridine / CH₂Cl₂ / 1 h / Ambient temperature

2: 62 percent / NaBH₄ / tetrahydrofuran; ethanol / 1.5 h / -35 °C

3: 70 percent / LiOH*H₂O / methanol / 3 h / Ambient temperature

With pyridine; chromium(VI) oxide; lithium hydroxide; sodium tetrahydroborate; In tetrahydrofuran; methanol; ethanol; dichloromethane;
DOI:10.1021/jm00183a018