Benzenaminium,4-[[4-(dimethylamino)phenyl]mercurio]-N,N-dimethyl-N-[2-oxo-2-[(tributylstannyl)oxy]ethyl]-,iodide (9CI)

Base Information

• Chemical Name: Benzenaminium,4-[[4-(dimethylamino)phenyl]mercurio]-N,N-dimethyl-N-[2-oxo-2-[(tributylstannyl)oxy]ethyl]-,iodide (9CI)
• CAS No.: 4325-40-0
• Molecular Formula: C₃₀H₄₉HgN₂O₂Sn*I
• Molecular Weight: 915.936
• Mol file: 4325-40-0.mol

Synonyms:(Carboxymethyl)[p-[[p-(dimethylamino)phenyl)mercuri]phenyl]dimethylammoniumiodide, O-tributyltin deriv. (7CI); Tin,tributyl[[N-[p-[[p-(dimethylamino)phenyl]mercuri]phenyl]-N-methylglycyl]oxy]-,methiodide; NSC 101552

Chemical Property of Benzenaminium,4-[[4-(dimethylamino)phenyl]mercurio]-N,N-dimethyl-N-[2-oxo-2-[(tributylstannyl)oxy]ethyl]-,iodide (9CI)

Chemical Property:

Purity/Quality:

85.0-99.8% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Benzenaminium,4-[[4-(dimethylamino)phenyl]mercurio]-N,N-dimethyl-N-[2-oxo-2-[(tributylstannyl)oxy]ethyl]-,iodide (9CI)

There total 3 articles about Benzenaminium,4-[[4-(dimethylamino)phenyl]mercurio]-N,N-dimethyl-N-[2-oxo-2-[(tributylstannyl)oxy]ethyl]-,iodide (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 52.0%

4,4'-mercuriobis(N,N-dimethylaniline) (4219-76-5) + tributylstannyl iodoacetate (73927-91-0) → ((C4H9)3SnOOCCH2Hg(C6H4N(CH3)2)2)(1+)*I(1-)=(C4H9)3SnOOCCH2Hg(C6H4N(CH3)2)2I (4325-40-0)

Guidance literature:

slight excess of tributyltinhalocarboxylate, equimolar amounts, 110 °C 15 min;

DOI:10.1021/jo01042a531

Reference yield:

Tributylzinnester des Acetylglycins (1801-43-0) → ((C4H9)3SnOOCCH2Hg(C6H4N(CH3)2)2)(1+)*I(1-)=(C4H9)3SnOOCCH2Hg(C6H4N(CH3)2)2I (4325-40-0)

Guidance literature:

Multi-step reaction with 3 steps

1: water; 1,4-dioxane

In 1,4-dioxane; water;

Reference yield:

bis(tri-n-butyltin)oxide (56-35-9) → ((C4H9)3SnOOCCH2Hg(C6H4N(CH3)2)2)(1+)*I(1-)=(C4H9)3SnOOCCH2Hg(C6H4N(CH3)2)2I (4325-40-0)

Guidance literature:

upstream raw materials:

4,4'-mercuriobis(N,N-dimethylaniline)

tributylstannyl iodoacetate

bis(tri-n-butyltin)oxide

Tributylzinnester des Acetylglycins