4219-76-5

Upstream product

• 586-77-6 4-bromo-N,N-dimethylaniline 
• 79175-36-3 4-dimethylaminophenylmercury hydroxide 
• 13190-50-6 4-dimethylaminophenyllithium 
• 23332-31-2 p-dimethylaminophenylmercury acetate 
• 121-69-7 N,N-dimethyl-aniline 

Downstream Products

• 18365-30-5 (C₂H₅)3SnC₆H₄-p-N(CH₃)2 
• 29972-74-5 (4-dimethylamino-phenyl)-phosphonous acid dichloride 
• 1017598-53-6 bis-(4-trimethylammonio-phenyl)-mercury 
• 121-69-7 N,N-dimethyl-aniline 
• 20683-98-1 4-N,N-dimethylaminophenylphosphinic acid 
• 106765-75-7 {(C₃H₇)3SnOOCCH₂C₁₆H₂₀HgN₂}⁽¹⁺⁾*Br^(1-)={(C₃H₇)3SnOOCCH₂C₁₆H₂₀HgN₂}Br 
• 4823-89-6 {(C₃H₇)3SnOOCCH₂C₁₆H₂₀HgN₂}⁽¹⁺⁾*I^(1-)={(C₃H₇)3SnOOCCH₂C₁₆H₂₀HgN₂}I 
• 4325-40-0 ((C₄H₉)3SnOOCCH₂Hg(C₆H₄N(CH₃)2)2)⁽¹⁺⁾*I^(1-)=(C₄H₉)3SnOOCCH₂Hg(C₆H₄N(CH₃)2)2I 
• 108064-19-3 ((C₄H₉)3SnOOCCH₂Hg(C₆H₄N(CH₃)2)2)⁽¹⁺⁾*Br^(1-)=(C₄H₉)3SnOOCCH₂Hg(C₆H₄N(CH₃)2)2Br 
• 68837-58-1 FHg(C₆H₄(N(CH₃)2)) 
• 99699-74-8 (CH₃)2NC₆H₄HgC₆H₄F 
• 81249-19-6 [Pt₂Cl₂(COC₆H₄N(CH₃)2)2(PCH₃(C₆H₅)2)2] 
• 99699-66-8 (CH₃)2NC₆H₄HgC₆H₄F 

Relevant academic research and scientific papers

Characterisation of the first authenticated organomercury hydroxide, 4-Me2NC6H4HgOH

4-Me2NC6H4HgOH was prepared from 4-Me2NC6H4HgOAc. Full characterisation showed that it crystallises as discrete molecules, the first example of a true organomercury hydroxide in the solid state. The structures of 4-Me2NC6H4HgOAc and (4-Me2NC6H4)2Hg are also discussed.

Synthesis and Interconversion of, and Restricted Rotation in, Phenyl Complexes of Ruthenium(II)

The preparation and characterization of a range of phenyl complexes of ruthenium(II) are reported.For many of the complexes there is a substantial barrier to rotation of the phenyl ligand about the metal-phenyl bond, and n.m.r. studies have shown how the rate of rotation is affected by changes in the ligands in the complexes.Reaction of complexes with phosphorus or arsenic ligands L provides a convenient route to : 31P and 13C n.m.r. studies have demonstrated the sequence of steps involved and the stereochemistry of the intermediates, showing the influence of the trans-labilizing and trans-directing effects of the phenyl ligand.