Nickel, [[alpha,alpha'-(ethylenedinitrilo)di-o-cresolato](2-)]-

Base Information

Chemical Name:Nickel, [[alpha,alpha'-(ethylenedinitrilo)di-o-cresolato](2-)]-
CAS No.:14167-20-5
Molecular Formula:C₁₆H₁₄N₂NiO₂
Molecular Weight:324.989
Hs Code.:
European Community (EC) Number:624-036-7
NSC Number:871
Mol file:14167-20-5.mol

Synonyms:14167-20-5;Nickel, [[alpha,alpha'-(ethylenedinitrilo)di-o-cresolato](2-)]-;2-[2-[(2-hydroxyphenyl)methylideneamino]ethyliminomethyl]phenol;nickel;Nickel, [[.alpha.,.alpha.'-(ethylenedinitrilo)di-o-cresolato](2-)]-;Nickel, ((2,2'-(1,2-ethanediylbis(nitrilomethylidyne))bis(phenolato))(2-)-N,N',O,O')-;Nickel, [[2,2'-[1,2-ethanediylbis(nitrilomethylidyne)]bis[phenolato]](2-)-N,N',O,O']-, (SP-4-2)-;NSC871;NSC-871;DKBSGGSJQXGHBV-OYJDLGDISA-L;Bis(salicylaldehyde)ethylenediiminatonickel;N,N'-Ethylenebis(salicylideniminato)nickel;Nickel, [N,N'-ethylenebis(salicylaldiminato)]-;[.ALPHA.,.ALPHA.-(ETHYLENEDINITRILO)DI-O-CRESOLATO(2-)]NICKEL;Nickel,[[2,2'-[1,2-ethanediylbis(nitrilomethylidyne)]bis[phenolato]](2-)-N,N',O,O']-

Suppliers and Price of Nickel, [[alpha,alpha'-(ethylenedinitrilo)di-o-cresolato](2-)]-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
N,N′-Bis(salicylidene)ethylenediaminonickel(II) 98%
5g
$ 128.00

American Custom Chemicals Corporation
N,N'-BIS(SALICYLIDENE)ETHYLENEDIAMINONICKEL(II) 98.00%
5G
$ 914.41

Total 7 raw suppliers

Chemical Property of Nickel, [[alpha,alpha'-(ethylenedinitrilo)di-o-cresolato](2-)]-

Chemical Property:

Melting Point:>150 °C (decomp)
Boiling Point:498.2°Cat760mmHg
Flash Point:193.6°C
PSA：58.20000
Density:g/cm³
LogP:2.10540
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:0
Exact Mass:326.056519
Heavy Atom Count:21
Complexity:304

Purity/Quality:

98%,99%, ^*data from raw suppliers

N,N′-Bis(salicylidene)ethylenediaminonickel(II) 98% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:T
Statements: 45-20/21/22-36/37/38-42/43
Safety Statements: 53-26-36/37/39-45

MSDS Files:: Total 1 MSDS from other Authors

Useful:

Canonical SMILES:C1=CC=C(C(=C1)C=NCCN=CC2=CC=CC=C2O)O.[Ni]
Uses Catalyst for:Covalent functionalization of multiwall carbon nanotubesReduction reactionsEpoxidation reactionsReduction and intramolecular cyclization

Technology Process of Nickel, [[alpha,alpha'-(ethylenedinitrilo)di-o-cresolato](2-)]-

There total 2 articles about Nickel, [[alpha,alpha'-(ethylenedinitrilo)di-o-cresolato](2-)]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 124890-89-7
rac-(OC₆H₄CH(CH₂SC₆H₅)NHCH₂CH₂NCHC₆H₄O)Ni

: 50-00-0,30525-89-4,61233-19-0
formaldehyd

: 1160066-31-8,14167-20-5
[N,N'-ethylenebis(salicylideneiminato)]nickel(II)

: 882-33-7
diphenyldisulfane

Guidance literature:: With O₂; In ethanol; Dissolving under stirring and heating at air.; Concg., cooling, filtn. gives Ni-complex, chromy. (silica gel, CH2Cl2/hexane) of the mother liquor gives diphenyl disulfide.;

Reference yield:

: {NiC₁₆H₁₄N₂O₂}*0.52C₆H₅NO₂

: 14167-20-5,1160066-31-8
nickel(II) salen

: 98-95-3,26969-40-4
nitrobenzene

Guidance literature:: higher temp.;

Reference yield: 94.0%

: 1295-35-8
bis(1,5-cyclooctadiene)nickel ⁽⁰⁾

: 14167-20-5,1160066-31-8
nickel(II) salen

: 84-11-7
9,10-phenanthrenequinone

: (bissalicylaldehyde-ethylenediiminato) nickel(II) nickel(II) (9,10-phenanthrenesemiquinone)2

Guidance literature:: In tetrahydrofuran; Ar atmosphere; addn. of soln. of org. compd. in THF to soln. of Ni(COD)2 in THF (room temp.), stirring (2 h), addn. of soln. of Ni(salen) in THF; elem. anal.;