cis-1-Propylmethyl ether

Base Information

• Chemical Name: cis-1-Propylmethyl ether
• CAS No.: 4188-68-5
• Molecular Formula: C4H8O
• Molecular Weight: 72.1069
• Hs Code.: 2909199090
• European Community (EC) Number: 609-966-3
• DSSTox Substance ID: DTXSID001308584
• Nikkaji Number: J590.739J
• Mol file: 4188-68-5.mol

Synonyms:cis-1-Propylmethyl ether;1-Propene, 1-methoxy-, (Z)-;4188-68-5;1-propene, 1-methoxy-, (1Z)-;Ether, methyl propenyl, (Z)-;cis-1-Propenyl methyl ether;cis-1-methoxy-propene;(Z)-1-Methoxypropene;cis-methyl propenyl ether;(1Z)-1-methoxyprop-1-ene;DTXSID001308584

Chemical Property of cis-1-Propylmethyl ether

Chemical Property:

• Vapor Pressure: 504mmHg at 25°C
• Boiling Point: 36.4°Cat760mmHg
• Flash Point: °C
• PSA: 9.23000
• Density: 0.762g/cm³
• LogP: 1.16640
• XLogP3: 1.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 1
• Exact Mass: 72.057514874
• Heavy Atom Count: 5
• Complexity: 30.6

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC=COC
• Isomeric SMILES: C/C=C\OC

Technology Process of cis-1-Propylmethyl ether

There total 4 articles about cis-1-Propylmethyl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

propylene glycol methyl ether acetate (108-65-6,142300-82-1) → methyl (Z)-prop-1-enyl ether (4188-68-5) + methylallylether (627-40-7)

Guidance literature:

at 500 ℃;

DOI:10.1016/0040-4020(59)80059-4

Reference yield:

Methoxyallene (13169-00-1) → methyl (Z)-prop-1-enyl ether (4188-68-5) + (E)-1-Methoxy-1-propen (4188-69-6) + methylallylether (627-40-7)

Guidance literature:

With p-H₂; BF4; In acetone; Product distribution; Ambient temperature; reactions in presence of different rhodium (I) catalysts;

DOI:10.1016/0040-4039(94)80110-X

Reference yield:

cyclopropyl methyl ether (540-47-6) → methane (34557-54-5,27936-85-2) + methyl (Z)-prop-1-enyl ether (4188-68-5) + (E)-1-Methoxy-1-propen (4188-69-6) + methylallylether (627-40-7)

Guidance literature:

at 361.9 - 420.9 ℃; under 28 Torr; Product distribution; Rate constant; Kinetics; for var. pyrolysis times;

DOI:10.1039/f19837901413

upstream raw materials:

propylene glycol methyl ether acetate

cyclopropyl methyl ether

Methoxyallene

Downstream raw materials:

(4R,5S)-5-Methoxy-4-methyl-2-phenyl-4,5-dihydro-oxazole

(4S,5S)-5-Methoxy-4-methyl-2-phenyl-4,5-dihydro-oxazole

phenyl isocyanate

(2E,4E,6E)-2,7-dimethyl-2,4,6-octatrienedial