Allyl methyl ether

Base Information

• Chemical Name: Allyl methyl ether
• CAS No.: 627-40-7
• Molecular Formula: C4H8O
• Molecular Weight: 72.1069
• Hs Code.: 29161900
• European Community (EC) Number: 210-997-6
• DSSTox Substance ID: DTXSID7060839
• Nikkaji Number: J27.122E
• Wikidata: Q72518115
• Mol file: 627-40-7.mol

Synonyms:Allyl methyl ether;627-40-7;3-methoxyprop-1-ene;3-Methoxy-1-propene;1-Propene, 3-methoxy-;Methyl allyl ether;Ether, allyl methyl;3-Methoxypropene;allylmethylether;EINECS 210-997-6;MFCD00008649;allylmethyl ether;4-Oxapent-1-ene;1-Methoxy-2-propene;methyl-2-propenyl ether;Methyl 2-propenyl ether;2-Propene, 3-methoxy-;CH2=CHCH2OCH3;Allyl methyl ether, 97%;DTXSID7060839;NIOSH/KM9160000;AllylMethylEther3-Methoxy-1-propene;TL 217;AKOS015916513;LS-67713;AM20100534;CS-0179384;FT-0616013;KM91600000;D88491;EN300-1662930;A833964

Chemical Property of Allyl methyl ether

Chemical Property:

• Vapor Pressure: 354mmHg at 25°C
• Melting Point: -115.8°C (estimate)
• Refractive Index: 1.3803
• Boiling Point: 46 °C at 760 mmHg
• Flash Point: - 23 °C
• PSA: 9.23000
• Density: 0.751 g/cm³
• LogP: 0.81880
• Storage Temp.: Refrigerator
• Water Solubility.: Insoluble in water
• XLogP3: 0.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 72.057514874
• Heavy Atom Count: 5
• Complexity: 24.8

Purity/Quality:

99% ^*data from raw suppliers

Allyl Methyl Ether >97.0%(GC) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F+XnF
• Hazard Codes: F+,Xn,F
• Statements: 11-19-36-22-12
• Safety Statements: 3/7-9-16-36/37/39-26

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: COCC=C
• Uses: Allyl methyl ether it used as pharmaceutical intermediate.

Technology Process of Allyl methyl ether

There total 72 articles about Allyl methyl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.6%

1-methoxy-2-propanol (107-98-2) → methylallylether (627-40-7)

Guidance literature:

With zirconium(IV) oxide; at 100 ℃; for 3h; Temperature; Reagent/catalyst;

Reference yield: 93.0%

allyl alcohol (107-18-6) + methyl iodide (74-88-4) → methylallylether (627-40-7)

Guidance literature:

With dimsylsodium; In dimethyl sulfoxide; Ambient temperature;

DOI:10.1021/jo00316a011

Reference yield: 88.0%

3,3-dimethoxyprop-1-ene (6044-68-4) → methylallylether (627-40-7)

Guidance literature:

With benzo[1,3,2]dioxaborole; In benzene; Ambient temperature;

DOI:10.1080/00397919108019775

upstream raw materials:

1,2-epithio-3-methoxypropane

triethyl phosphite

methanol

3-ethoxyprop-1-ene

Downstream raw materials:

1,2-dibromo-3-methoxypropane

methyl 2-methoxy-4-pentenoate

(2-(methoxymethyl)cyclopropyl)benzene

1-(1-Hydroxycyclohexyl)allylmethylether

Refernces

• 1、 Geng, Jiao,Hu, Xingbang,Liu, Qiang,Wu, Youting,Yang, Liu,Yao, Chenfei. "Controlling the Lewis Acidity and Polymerizing Effectively Prevent Frustrated Lewis Pairs from Deactivation in the Hydrogenation of Terminal Alkynes". . p. 3685 - 3690. Retrieved 2021/05/31.
• 2、 Maulbetsch, Theo,Jürgens, Eva,Kunz, Doris. "Deoxygenation of Epoxides with Carbon Monoxide". . p. 10634 - 10640. Retrieved 2020/07/30.