2-Iodo-1,1'-binaphthalene

Base Information

Chemical Name:2-Iodo-1,1'-binaphthalene
CAS No.:402745-52-2
Molecular Formula:C₂₀H₁₃I
Molecular Weight:380.228
Hs Code.:
DSSTox Substance ID:DTXSID10562982
Nikkaji Number:J1.036.626G
Wikidata:Q82447324
Mol file:402745-52-2.mol

Synonyms:2-Iodo-1,1'-binaphthalene;iodobinaphthyl;402745-52-2;SCHEMBL9756475;DTXSID10562982

Suppliers and Price of 2-Iodo-1,1'-binaphthalene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 2-Iodo-1,1'-binaphthalene

Chemical Property:

PSA：0.00000
LogP:6.26460
XLogP3:6.7
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:1
Exact Mass:380.00620
Heavy Atom Count:21
Complexity:352

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC=C2C(=C1)C=CC=C2C3=C(C=CC4=CC=CC=C43)I

Technology Process of 2-Iodo-1,1'-binaphthalene

There total 1 articles about 2-Iodo-1,1'-binaphthalene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 882-33-7
diphenyldisulfane

: (S_a)-2,2'-diiodo-1,1'-binaphthyl

: (S)-(2'-iodo-[1,1'-binaphthalen]-2-yl)(phenyl)sulfane

: 128444-85-9,402745-52-2
(R_a)-2-iodo-1,1'-binaphthalene

Guidance literature:: (S_a)-2,2'-diiodo-1,1'-binaphthyl; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 1h; Inert atmosphere;

diphenyldisulfane; In tetrahydrofuran; hexane; at -78 - 20 ℃; Overall yield = 216 mg; Inert atmosphere;
DOI:10.1055/s-0037-1610697

Reference yield: 91.0%

: 536-74-3
phenylacetylene

: 128444-85-9,402745-52-2
(R_a)-2-iodo-1,1'-binaphthalene

: (R_a)-2-(phenylethynyl)-1,1'-binaphthalene

Guidance literature:: With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine; at 60 ℃; for 12h; Schlenk technique; Inert atmosphere;
DOI:10.1021/jacs.0c05283

Reference yield: 82.0%

: 4559-70-0
Diphenylphosphine oxide

: 128444-85-9,402745-52-2
(R_a)-2-iodo-1,1'-binaphthalene

: (R_a)-[1,1'-binaphthalen]-2-yldiphenylphosphine oxide

Guidance literature:: With palladium diacetate; N-ethyl-N,N-diisopropylamine; 1,4-di(diphenylphosphino)-butane; In dimethyl sulfoxide; at 120 ℃; for 12h;
DOI:10.1021/jacs.0c05283