alcaligin

Base Information

Chemical Name:alcaligin
CAS No.:117959-43-0
Molecular Formula:C₁₆H₂₈N₄O₈
Molecular Weight:404.42
Hs Code.:

Synonyms:1,6,11,16-Tetraazacycloeicosane-2,5,12,15-tetrone,1,8,11,18-tetrahydroxy-, [8S-(8R*,18R*)]-;1,8(S),11,18(S)-Tetrahydroxy-1,6,11,16-tetraazacycloeicosane-2,5,12,15-tetrone;Alcaligin

Suppliers and Price of alcaligin

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 2 raw suppliers

Chemical Property of alcaligin

Chemical Property:

PSA：179.74000
LogP:-1.73620

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of alcaligin

There total 5 articles about alcaligin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 135227-44-0
1,8(S),11,18(S)-Tetrakis(benzyloxy)-1,6,11,16-tetraazacycloeicosane-2,5,12,15-tetrone

: 117959-43-0
alcaligin

Guidance literature:: With hydrogen; palladium on activated charcoal; In methanol; for 15h; under 760 Torr;
DOI:10.1021/jo00019a017

Reference yield:

: 135227-41-7
10-(tert-Butoxycarbonyl)-5,8(S)-bis(benzyloxy)-4-oxo-5,10-diazadecanoic Acid

: 117959-43-0
alcaligin

Guidance literature:: Multi-step reaction with 5 steps

1: 91 percent / diphenyl phosphorazidate, NEt₃ / dimethylformamide / 1.) 0-15 deg C, 10 h, 2.) room temperature 1-2 d

2: 85 percent / pyridine / 2 h / 80 °C

3: 1.59 g / CH₂Cl₂ / 0.88 h / Ambient temperature

4: 66 percent / NEt₃, diphenyl phosphorazidate / dimethylformamide / 110 h / 0 - 7.5 °C

5: 78 percent / H₂ / 10percent Pd-C / methanol / 15 h / 760 Torr

With pyridine; diphenyl phosphoryl azide; hydrogen; triethylamine; palladium on activated charcoal; In methanol; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/jo00019a017

Reference yield:

: 135227-42-8
1-(tert-Butoxycarbonyl)-3(S),6,13(S),16-tetrakis(benzyloxy)-1,6,11,16-tetraazahexadecane-7,10-dione

: 117959-43-0
alcaligin

Guidance literature:: Multi-step reaction with 4 steps

1: 85 percent / pyridine / 2 h / 80 °C

2: 1.59 g / CH₂Cl₂ / 0.88 h / Ambient temperature

3: 66 percent / NEt₃, diphenyl phosphorazidate / dimethylformamide / 110 h / 0 - 7.5 °C

4: 78 percent / H₂ / 10percent Pd-C / methanol / 15 h / 760 Torr

With pyridine; diphenyl phosphoryl azide; hydrogen; triethylamine; palladium on activated charcoal; In methanol; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/jo00019a017