Cyclohexanethiol, silver(1+) salt

Base Information

• Chemical Name: Cyclohexanethiol, silver(1+) salt
• CAS No.: 4081-37-2
• Molecular Formula: C6H12S.Ag
• Molecular Weight: 223.088
• Mol file: 4081-37-2.mol

Synonyms:

Chemical Property of Cyclohexanethiol, silver(1+) salt

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Cyclohexanethiol, silver(1+) salt

There total 3 articles about Cyclohexanethiol, silver(1+) salt which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Cyclohexanethiol (1569-69-3) + silver nitrate → silver(I) cyclohexanethiolate (4081-37-2)

Guidance literature:

In water; acetone; slow addn. of soln. of AgNO3 in water to a soln. of thiol in acetone; equimolar amts. of educts; washing with water; evapg.; recrystg.;

Reference yield:

sodium cyclohexanethiolate (50729-68-5) + silver nitrate → silver(I) cyclohexanethiolate (4081-37-2)

Guidance literature:

In methanol; mixing, according to: T. H. Joo, M. S. Kim, K. Kim, J. Raman. Spectrosc.18 (1987) 57; washing precipitates (methanol);

DOI:10.1016/S0022-2860(98)00895-3

Reference yield:

Cyclohexanethiol (1569-69-3) + silver(I) chloride → silver(I) cyclohexanethiolate (4081-37-2)

Guidance literature:

In methanol; for 0.25h;

DOI:10.1021/acs.inorgchem.7b02568

upstream raw materials:

Cyclohexanethiol

sodium cyclohexanethiolate

Refernces

• 1、 Cho, Seung Il,Park, Eun Sun,Kim, Kwan,Kim, Myung Soo. "Spectral correlation in the adsorption of aliphatic mercaptans on silver and gold surfaces: Raman spectroscopic and computational study". . p. 83 - 92. Retrieved 2007/10/03.