1,1,1,3,3,3-Hexafluoro-2-iodopropane

Base Information

• Chemical Name: 1,1,1,3,3,3-Hexafluoro-2-iodopropane
• CAS No.: 4141-91-7
• Molecular Formula: C3HF6I
• Molecular Weight: 277.93500
• Hs Code.: 2903799090
• Mol file: 4141-91-7.mol

Synonyms:1,1,1,3,3,3-HEXAFLUORO-2-IODO-PROPANE;1,1,1,3,3,3-hexafluoroisopropyl iodide;Propane,1,1,1,3,3,3-hexafluoro-2-iodo;2H-2-Iod-hexafluorpropan;2-Jod-1,1,1,3,3,3-hexafluorpropan;2-Hydro-2-jod-hexafluorpropan;Hexafluorisopropyljodid;

Chemical Property of 1,1,1,3,3,3-Hexafluoro-2-iodopropane

Chemical Property:

• Vapor Pressure: 209.783mmHg at 25°C
• Boiling Point: 59.959oC at 760 mmHg
• Flash Point: 12.781oC
• PSA: 0.00000
• Density: 2.137g/cm3
• LogP: 2.91460

Purity/Quality:

99%, ^*data from raw suppliers

1,1,1,3,3,3-HexafluoroisopropylIodide ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,1,1,3,3,3-Hexafluoro-2-iodopropane

There total 3 articles about 1,1,1,3,3,3-Hexafluoro-2-iodopropane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

1,1,2,2,3,3,4,4,4-nonafluoro-butane-1-sulfonic acid 2,2,2-trifluoro-1-trifluoromethyl-ethyl ester (118334-96-6) → 1,1,1,3,3,3-Hexafluoroisopropyl iodide (4141-91-7)

Guidance literature:

With sodium iodide; In acetylacetone; at 110 ℃; for 16h;

DOI:10.1021/jo00267a036

Reference yield: 59.0%

2H-pentafluoropropene (690-27-7) → 1,1,1,3,3,3-Hexafluoroisopropyl iodide (4141-91-7)

Guidance literature:

With hydrogen fluoride; boron trifluoride; Iodine monochloride; at 50 ℃; for 18h;

DOI:10.1021/jo961271o

Reference yield:

→ 1,1,1,3,3,3-Hexafluoroisopropyl iodide (4141-91-7)

Guidance literature:

Hexafluorisobuttersaeure-K-Salz, Jod, KI, W., 70-80grad;

upstream raw materials:

1,1,2,2,3,3,4,4,4-nonafluoro-butane-1-sulfonic acid 2,2,2-trifluoro-1-trifluoromethyl-ethyl ester

2H-pentafluoropropene

Refernces

• 1、 Hanack, Michael,Ullmann, Joerg. "Facile Synthesis of Trifluoro- and Hexafluoroisopropyl Halides". . p. 1432 - 1435. Retrieved 2007/10/02.