690-27-7

Usage

Uses

Used in Refrigeration Industry:
1,1,3,3,3-Pentafluoropropene is used as a refrigerant due to its desirable thermodynamic properties, offering an efficient cooling solution while minimizing environmental harm.
Used in Fluoropolymer Production:
In the chemical industry, 1,1,3,3,3-Pentafluoropropene is utilized as a monomer in the production of fluoropolymers, which are known for their exceptional chemical resistance and thermal stability.
Used in Foam-blowing Agents:
1,1,3,3,3-Pentafluoropropene is employed as a foam-blowing agent in the manufacturing of insulation materials, providing a lightweight and energy-efficient option for various applications.
Used in Aerosol Propellants:
1,1,3,3,3-PENTAFLUOROPROPENE is used as an aerosol propellant, enabling the efficient dispensing of products in spray form across different consumer and industrial markets.
Used in Fire Protection Systems:
1,1,3,3,3-Pentafluoropropene is utilized in fire protection systems, where its properties contribute to effective fire suppression and safety measures.
Given the compound's multifaceted applications and its status as a regulated greenhouse gas, the use of 1,1,3,3,3-Pentafluoropropene underscores the balance between industrial necessity and environmental stewardship.

InChI:InChI=1/C3HF5/c4-2(5)1-3(6,7)8/h1H

Upstream product

• 460-92-4 1-chloro-1,1,3,3,3-pentafluoropropane 
• 371-75-5 1,1,1,3,3-pentafluoro-3-iodo-propane 
• 460-88-8 1-bromo-1,1,3,3,3-pentafluoro-propane 
• 431-86-7 1,1,1,3,3-pentafluoro-2,3-dichloropropane 
• 460-61-7 3-bromo-1,1,3,3-tetrafluoro-propene 
• 461-68-7 1,1,3,3-tetrafluoro-1,2-propadiene 
• 674-03-3 1,1,3,3-tetrafluoro-3-iodo-propene 
• 920-66-1 1,1,1,3',3',3'-hexafluoro-propanol 
• 90624-72-9 C₃HF₆^(1-) 
• 75-65-0 tert-butyl alcohol 
• 1652-80-8 2,2-dichloro-1,1,1,3,3,3-hexafluoro-propane 
• 76-18-6 2-Chloro-F-propane 
• 1599-41-3 2,2,3-trichloro-1,1,1,3,3-pentafluoropropane 
• 690-39-1 1,1,1,3,3,3-hexafluoropropane 

Downstream Products

• 382-25-2 1,1,1,3,3-pentafluoro-3-iodo-2-trifluoromethyl-propane 
• 75-46-7 trifluoromethan 
• 76-16-4 Hexafluoroethane 
• 431-78-7 2,3-Dibromo-1,1,1,3,3-pentafluoropropane 
• 431-86-7 1,1,1,3,3-pentafluoro-2,3-dichloropropane 
• 359-59-1 1-chloro-1,1,3,3,3-pentafluoro-2-iodo-propane 
• 58335-41-4 Phenyl-cis-1,3,3,3-tetrafluorprop-1-enylsulfid 
• 58335-42-5 Phenyl-trans-1,3,3,3-tetrafluorprop-1-enylsulfid 
• 690-39-1 1,1,1,3,3,3-hexafluoropropane 
• 460-73-1 1,1,1,3,3-Pentafluoropropane 
• 137470-79-2 perfluoro-(3-methyl-2,1-benzisoxazole) 
• 137445-20-6 tetrafluoro-1-nitro-4-(2,2,2-trifluoroethyl)benzene 
• 137445-19-3 perfluoro-4-(2H-hexafluoroisopropyl)-1-nitrobenzene 
• 137445-17-1 tetrafluoro-4-(2,2,2-trifluoroethyl)benzonitrile 

Relevant academic research and scientific papers

Preparation method of 1,1,3,3,3-pentafluoropropylene

The invention discloses a preparation method of 1,1,3,3,3-pentafluoropropylene. The preparation method comprises the following steps: (1) carrying out a reaction on halgen-containing inorganic salt and sevofluoroisobutenyl methyl ether in a first aprotic solvent, adding water into the solution to stir, cool and filter after the reaction, and rectifying the filtrate to obtain hexafluoroisobutyric acid; and (2) carrying out a reaction on the hexafluoroisobutyric acid obtained in the step (1) and a hydrogen ion capturing agent, collecting a generated gas phase product and cooling the product to obtain the 1,1,3,3,3-pentafluoropropylene product. The preparation method has the advantages of being simple in process, environment-friendly, low in cost and green and environment-friendly.

Reactions of fluoroalk-1-en-1-yltrifluoroborate and perfluoroalk-1-yn-1- yltrifluoroborate salts and selected hydrocarbon analogues with hydrogen fluoride and with halogenating agents in aHF and in basic solvents

The relative rate of the electrophilic hydrodeboration of K[R′BF 3] with HF (27-100%) diminishes in the series R′ = C 4H9CC > C4F9CFCFCC > CF 2C(CF3) > C3F7CC ～ (CF 3)2CFCC > CF3CC. When R′ = CF 3CC the new salt K[CF3CH2-CF2BF 3] was obtained by addition of HF besides CF3CCH and K[BF4]. Small amounts of water caused the formation of K[CF 3CH2-C(O)BF3] as a by-product. The electrophilic halofluorination of perfluoroalkenyltrifluoroborate salts with NCS or NBS in aHF (anhydrous HF) led to K[RFCFHal-CF2BF 3] (from K[RFCFCFBF3]) and K[R FCHal2-CF2BF3] (from K[R FCHalCFBF3] and K[RFCCBF3]) (Hal = Cl, Br). Treatment of K[RFCFCFBF3] and K[R FCCBF3] with 5% F2/N2 in MeCN gave the corresponding salts K[RFCF2-CF2BF 3] in 16-25% isolated yield. Reactions of K[trans-C4F 9CFCFBF3] with Cl2 in MeOH resulted in K[C 4F9CFCl-C(O)BF3] (major product). The latter was also obtained in reactions of K[trans-C4F9CFCFBF 3] with Cl2 in MeCN or sulfolane after sequential methanolysis of the primarily formed products. In contrast, the salts K[RCFCFBF3] (R = CnF2n+1, trans-C 4H9) and K[CF3CCBF3] underwent bromodeboration to RCFCFBr and CF3CCBr, respectively, when they were reacted with bromine in the polar solvents MeOH, MeCN, or sulfolane.

PROCESS FOR DEHYDROHALOGENATION OF HALOGENATED ALKANES

A process for the manufacture of halogenated olefins in semi-batch mode by dehydrohalogenation of halogenated alkanes in the presence of an aqueous base such as KOH which simultaneously neutralizes the resulting hydrogen halide. During the process, aqueous base is continuously added to the haloalkane which results in better yields, lower by-product formation and safer/more controllable operation.

PROCESS FOR THE PRODUCTION OF CHLORINATED AND/OR FLUORINATED PROPENES

The present invention provides one-step processes for the production of chlorinated and/or fluorinated propenes. The processes provide good product yield with low, e.g., less than about 20%, or even less than 10%, concentrations of residues/by-products. Advantageously, the processes may be conducted at low temperatures than 500° C. so that energy savings are provided, and/or at higher pressures so that high throughputs may also be realized. The use of catalysts or initiators may provide additional enhancements to conversion rates and selectivity, as may adjustments to the molar ratio of the reactants.

Method of dechlorinating organic compounds comprising vicinal chlorides

Provided is a method for selectively preparing 2-chloropentafluoropropene comprising catalytic dechlorination of 1,2,2-trichloro-1,1,3,3,3-pentafluoropropane in the presence of hydrogen and a noble metal catalyst. Also provided is method for dechlorinating a vicinal chloride substituted organic compound using a palladium/barium sulfate catalyst.

PREPARATION OF HALOGEN AND HYDROGEN CONTAINING ALKENES OVER METAL FLUORIDE CATALYSTS

Halogenated alkenes, especially fluorinated alkenes can be prepared from halogenated and fluorinated alkanes, respectively, by dehydrohalogenation or dehydrofluorination in the presence of a high-surface metal fluoride or oxifluoride. Preferably, trifluoroethylene, pentafluoropropene, tetrafluorobutenes or trifluorobutadiene are prepared. Aluminium fluoride is highly suitable. The metal fluoride or oxifluoride can be applied supported on a carrier.

PROCESSES FOR SEPARATION OF FLUOROOLEFINS FROM HYDROGEN FLUORIDE BY AZEOTROPIC DISTILLATION

The present disclosure relates to a process for separating a fluoroolefin from a mixture comprising hydrogen fluoride and fluoroolefin, comprising azeotropic distillation both with and without an entrainer. In particular are disclosed processes for separating any of HFC-1225ye, HFC-1234ze, HFC-1234yf or HFC-1243zf from HF.

PROCESS FOR THE PRODUCTION OF 1,1,1,3,3,3-HEXAFLUOROPROPANE

A process for the preparation of 1,1,1,3,3,3-hexafluoropropane is disclosed. The process involves (a) contacting at least one halopropane of the formula CF3CH2CHyX3-y (where each X is independently F, Cl or Br, and y is 3, 2, or 1) with Cl?2#191 in the presence of light or a free radical initiator to produce a mixture comprising CF3CH2CCIyX3-y; (b) contacting the CF3CH2CCIyX3-y produced in step (a) with HF, optionally in the presence of a fluorination catalyst, to produce a product mixture comprising CF3CH2CF3; and (c) recovering CF3CH2CF3 from the mixture produced in step (b).

Noncatalytic manufacture of 1,1,3,3,3-pentafluoropropene from 1,1,1,3,3,3-hexafluoropropane

1,1,3,3,3-Pentafluoropropene (CF3CH═CF2, HFC-1225zc) can be produced by pyrolyzing 1,1,1,3,3,3-hexafluoropropane (CF3CH2CF3, HFC-236fa) in the absence of dehydrofluorination catalyst at temperatures of from about 700° C. to about 1000° C. and total pressures of about atmosphere pressure in an empty, tubular reactor, the interior surfaces of which comprise materials of construction resistant to hydrogen fluoride.