Chloro(diphenyl)(prop-2-en-1-yl)silane

Base Information

• Chemical Name: Chloro(diphenyl)(prop-2-en-1-yl)silane
• CAS No.: 41422-93-9
• Molecular Formula: C15H15ClSi
• Molecular Weight: 258.823
• DSSTox Substance ID: DTXSID90548042
• Wikidata: Q82426624
• Mol file: 41422-93-9.mol

Synonyms:41422-93-9;Chloro(diphenyl)(prop-2-en-1-yl)silane;SCHEMBL5491545;DTXSID90548042

Chemical Property of Chloro(diphenyl)(prop-2-en-1-yl)silane

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 4
• Exact Mass: 258.0631547
• Heavy Atom Count: 17
• Complexity: 221

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=CC[Si](C1=CC=CC=C1)(C2=CC=CC=C2)Cl

Technology Process of Chloro(diphenyl)(prop-2-en-1-yl)silane

There total 6 articles about Chloro(diphenyl)(prop-2-en-1-yl)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

diphenylsilyl dichloride (80-10-4) + allylsamarium bromide (346713-20-0) → allyl(chloro)diphenylsilane (41422-93-9)

Guidance literature:

In tetrahydrofuran; at 20 ℃; for 1h;

DOI:10.1016/j.jorganchem.2006.07.023

Reference yield: 96.0%

allyl bromide (106-95-6) + diphenylsilyl dichloride (80-10-4) → diallyldiphenylsilane (10519-88-7) + allyl(chloro)diphenylsilane (41422-93-9)

Guidance literature:

allyl bromide; With indium; In 1,3-dimethylimidazolidine; at 20 ℃; for 1h;

diphenylsilyl dichloride; In 1,3-dimethylimidazolidine; at 70 ℃; for 3h;

DOI:10.1016/j.jorganchem.2008.08.028

Reference yield: 70.0%

Allyl-(2-chloro-propyl)-diphenyl-silane → allyl(chloro)diphenylsilane (41422-93-9) + Chloro-(2-methyl-pent-4-enyl)-diphenyl-silane

Guidance literature:

Heating;

DOI:10.1016/S0022-328X(00)85657-0

upstream raw materials:

allyltrichlorosilane

diphenylsilyl dichloride

allylsamarium bromide

diallyldiphenylsilane

Downstream raw materials:

3-[(R)-2-(Allyl-diphenyl-silanyloxy)-1-phenyl-ethyl]-6-methyl-3,6-diaza-bicyclo[3.1.0]hexane-2,4-dione

(2R)-2-allyldiphenylsilanyloxy-2-[5,6-dimethoxy-5,6-dimethyl-1,4-dioxan-2-yl]acetonitrile

1-(allyldiphenylsilyl)-2-(1-hexynyl)benzene

[2-(1-allyl-(E)-1-hexenyl)phenyl]dimethylsilyl methyl ether