DIETHYL 2-OXOHEPTANE-1,7-DICARBOXYLATE

Base Information

• Chemical Name: DIETHYL 2-OXOHEPTANE-1,7-DICARBOXYLATE
• CAS No.: 42212-75-9
• Molecular Formula: C11H18O5
• Molecular Weight: 230.261
• Hs Code.: 2918300090
• Mol file: 42212-75-9.mol

Synonyms:oxo-2 pimelate d'ethyle;ethyl oxopentanoate;diethyl 2-oxopimelate;2-Oxopentanoic acid ethyl ester;2-Oxo-valeriansaeure-aethylester;Ethyl 2-oxo-pentanoate;Ethyl 2-oxovalerate;Pentanoic acid,2-oxo-,ethyl ester;ethyl 2-oxo-pimelate;ethyl 2-oxopentoate;2-oxo-valeric acid ethyl ester;

Chemical Property of DIETHYL 2-OXOHEPTANE-1,7-DICARBOXYLATE

Chemical Property:

• Vapor Pressure: 0.000962mmHg at 25°C
• Boiling Point: 302.9oC at 760 mmHg
• Flash Point: 129.1oC
• PSA: 69.67000
• Density: 1.075g/cm3
• LogP: 1.24210

Purity/Quality:

97% ^*data from raw suppliers

Diethyl2-oxoheptane-1,7-dicarboxylate 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of DIETHYL 2-OXOHEPTANE-1,7-DICARBOXYLATE

There total 3 articles about DIETHYL 2-OXOHEPTANE-1,7-DICARBOXYLATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 56.0%

2-(4-Ethoxycarbonyl-butyl)-[1,3]dithiolane-2-carboxylic acid ethyl ester → diethyl 2-oxopimelate (42212-75-9)

Guidance literature:

With N-Bromosuccinimide; silver nitrate; In acetonitrile; for 0.05h;

DOI:10.1021/ja9808402

Reference yield: 41.0%

ethyl 2-(4-ethoxycarbonylbutyl)-1,3-dithiane-2-carboxylate (452336-69-5) → diethyl 2-oxopimelate (42212-75-9)

Guidance literature:

With 2,6-dimethylpyridine; N-Bromosuccinimide; silver nitrate; In water; acetonitrile; at 0 - 20 ℃; for 0.5h;

DOI:10.1021/jo0201631

Reference yield:

ethyl 5-bromovalerate (14660-52-7) → diethyl 2-oxopimelate (42212-75-9)

Guidance literature:

Multi-step reaction with 2 steps

1.1: n-butyllithium / hexane; tetrahydrofuran / 0.5 h / -78 °C

1.2: 75 percent / hexane; tetrahydrofuran / 0.5 h / -78 - 20 °C

2.1: 41 percent / N-bromosuccinimide; silver nitrate; 2,6-lutidine / acetonitrile; H₂O / 0.5 h / 0 - 20 °C

With 2,6-dimethylpyridine; N-Bromosuccinimide; n-butyllithium; silver nitrate; In tetrahydrofuran; hexane; water; acetonitrile;

DOI:10.1021/jo0201631

upstream raw materials:

ethyl 2-(4-ethoxycarbonylbutyl)-1,3-dithiane-2-carboxylate

ethyl 5-bromovalerate

Downstream raw materials:

methyl-2 ethoxycarbonyl-5 tetrahydro-4,5,6,7 benzothiazole

6,7-dihydrobenzo[d]thiazol-4(5H)-one

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 42212-75-9 DIETHYL 2-OXOHEPTANE-1,7-DICARBOXYLATE

Send

Send

Metric Ton KG G Pound L ML

Send

Send