Methanesulfonyl iodide

Base Information

• Chemical Name: Methanesulfonyl iodide
• CAS No.: 42790-82-9
• Molecular Formula: CH3IO2S
• Molecular Weight: 206.004
• DSSTox Substance ID: DTXSID50502408
• Nikkaji Number: J2.629.457F
• Wikidata: Q82355399
• Mol file: 42790-82-9.mol

Synonyms:Methanesulfonyl iodide;42790-82-9;SCHEMBL1728092;DTXSID50502408;ONQHJHZPCWQDOO-UHFFFAOYSA-N

Chemical Property of Methanesulfonyl iodide

Chemical Property:

• PSA: 42.52000
• LogP: 1.46180
• XLogP3: 0.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 205.88985
• Heavy Atom Count: 5
• Complexity: 95.3

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CS(=O)(=O)I

Technology Process of Methanesulfonyl iodide

There total 1 articles about Methanesulfonyl iodide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C14H26O4PSSi(1+)*I(1-) → methanesulphonyl iodide (42790-82-9) + trimethylsilyl tert-butylphenylphosphinate (97730-09-1)

Guidance literature:

With 2,6-dimethylpyridine; In dichloromethane; at 10 ℃; Yield given;

Reference yield: 72.0%

methanesulphonyl iodide (42790-82-9) + D-limonene (5989-27-5,555-08-8,8022-90-0,9003-73-0,95327-98-3) → (R)-4-((Z)-2-Methanesulfonyl-1-methyl-vinyl)-1-methyl-cyclohexene + (R)-4-((E)-2-Methanesulfonyl-1-methyl-vinyl)-1-methyl-cyclohexene (121881-29-6)

Guidance literature:

Yield given;

DOI:10.1039/c39880000702

Reference yield: 57.2%

styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + methanesulphonyl iodide (42790-82-9) → 1-iodo-2-(methanesulfonyl)-1-phenylethane (71964-07-3)

Guidance literature:

With triethylaminium halide; copper dichloride; In acetonitrile; at 20 - 25 ℃;

DOI:10.1021/jo01291a006

Downstream raw materials:

1-iodo-2-(methanesulfonyl)-1-phenylethane

(R)-4-((E)-2-Methanesulfonyl-1-methyl-vinyl)-1-methyl-cyclohexene

methanesulfonate

sodium methansulfinate