71964-07-3Relevant academic research and scientific papers
Metal-free iodine-mediated synthesis of vinyl sulfones at room temperature using water as solvent
Zhang, Ning,Yang, Daoshan,Wei, Wei,Yuan, Li,Cao, Youjuan,Wang, Hua
, p. 37013 - 37017 (2015)
Metal-free efficient iodine-mediated synthesis of vinyl sulfones utilizing aryl sulfinates and alkenes has been realized under mild conditions in water. Notably, sodium methanesulfinate was used in this transformation, affording the β-iodo sulfones in goo
Copper-Catalyzed Additions of Sulfonyl Iodides to Simple and Cyclic Alkenes
Liu, Lilian Kao,Chi, Y.,Jen, Kwan-Yue
, p. 406 - 410 (2007/10/02)
A convenient synthesis for various β-iodo sulfones has been developed.The reaction involves additions of alkane- and arenesulfonyl iodides to simple and cyclic alkenes under the catalytic action of copper(II) chloride.The favored stereochemical results for cyclic alkenes have been rationalized in terms of stepwise addition of both portions of the addend from the diaxial direction.
