alpha-D-Glucopyranose, 2,3,4,6-tetrakis-O-(phenylmethyl)-, 1-(4-nitrobenzoate)

Base Information

Chemical Name:alpha-D-Glucopyranose, 2,3,4,6-tetrakis-O-(phenylmethyl)-, 1-(4-nitrobenzoate)
CAS No.:4196-36-5
Molecular Formula:C41H39NO9
Molecular Weight:689.762
Hs Code.:
Mol file:4196-36-5.mol

Synonyms:4196-36-5;alpha-D-Glucopyranose, 2,3,4,6-tetrakis-O-(phenylmethyl)-, 1-(4-nitrobenzoate);SCHEMBL9164604;1-O-(4-NITROBENZOYL)-2,3,4,6-TETRA-O-BENZYL-ALPHA-D-GLUCOPYRANOSE;(2R,3R,4S,5R,6R)-3,4,5-Tris(benzyloxy)-6-((benzyloxy)methyl)tetrahydro-2H-pyran-2-yl 4-nitrobenzoate;[(2R,3R,4S,5R,6R)-3,4,5-Tris(phenylmethoxy)-6-(phenylmethoxymethyl)oxan-2-yl] 4-nitrobenzoate

Suppliers and Price of alpha-D-Glucopyranose, 2,3,4,6-tetrakis-O-(phenylmethyl)-, 1-(4-nitrobenzoate)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of alpha-D-Glucopyranose, 2,3,4,6-tetrakis-O-(phenylmethyl)-, 1-(4-nitrobenzoate)

Chemical Property:

Vapor Pressure:3.53E-25mmHg at 25°C
Refractive Index:1.636
Boiling Point:793.7°Cat760mmHg
Flash Point:258°C
Density:1.29g/cm³
XLogP3:7
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:9
Rotatable Bond Count:16
Exact Mass:689.26248182
Heavy Atom Count:51
Complexity:1010

Purity/Quality:: 99%, ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC=C(C=C1)COCC2C(C(C(C(O2)OC(=O)C3=CC=C(C=C3)[N+](=O)[O-])OCC4=CC=CC=C4)OCC5=CC=CC=C5)OCC6=CC=CC=C6
Isomeric SMILES:C1=CC=C(C=C1)COC[C@@H]2[C@H]([C@@H]([C@H]([C@H](O2)OC(=O)C3=CC=C(C=C3)[N+](=O)[O-])OCC4=CC=CC=C4)OCC5=CC=CC=C5)OCC6=CC=CC=C6

Technology Process of alpha-D-Glucopyranose, 2,3,4,6-tetrakis-O-(phenylmethyl)-, 1-(4-nitrobenzoate)

There total 5 articles about alpha-D-Glucopyranose, 2,3,4,6-tetrakis-O-(phenylmethyl)-, 1-(4-nitrobenzoate) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 90357-89-4
2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl trichloroacetimidate

: 62-23-7
4-nitro-benzoic acid

: 4196-36-5
2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl 4-nitrobenzoate

Guidance literature:: In dichloromethane; at 20 ℃; for 1.5h; Solvent; Kinetics; Inert atmosphere;
DOI:10.1016/j.carres.2013.09.011

Reference yield:

: 4291-69-4,6386-24-9,6564-72-3,59531-24-7,69257-52-9,78184-89-1,78609-16-2,78609-17-3,78609-18-4,96553-53-6,104111-61-7,131347-08-5,4132-28-9
2,3,4,6-Tetra-O-benzyl-D-glucopyranose

: 4196-36-5
2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl 4-nitrobenzoate

Guidance literature:: Multi-step reaction with 2 steps

1: potassium carbonate / dichloromethane / 12 h / 20 °C / Inert atmosphere

2: dichloromethane / 1.5 h / 20 °C / Inert atmosphere

With potassium carbonate; In dichloromethane;
DOI:10.1016/j.carres.2013.09.011

Reference yield:

: 6564-72-3
2,3,4,6-tetra-O-benzyl-D-glucopyranose

: 693-13-0
diisopropyl-carbodiimide

: 62-23-7
4-nitro-benzoic acid

: 63087-91-2
1-O-p-nitrobenzoyl-2,3,4,6-tetra-O-benzyl-β-D-glucopyranose

: 4196-36-5
2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl 4-nitrobenzoate

Guidance literature:: With copper(l) chloride; Yield given. Multistep reaction. Yields of byproduct given; 1.) CHCl₃, 2 d, r.t.; 2.) CHCl₃, 1 h, r.t.;
DOI:10.1016/0008-6215(82)85008-8