1-deoxy-1-(C-2',4',6'-trimethoxyphenyl) 2,3,4,6-tetra-O-benzyl-β-D-glucopyranoside

Base Information

• Chemical Name: 1-deoxy-1-(C-2',4',6'-trimethoxyphenyl) 2,3,4,6-tetra-O-benzyl-β-D-glucopyranoside
• CAS No.: 82300-67-2
• Molecular Formula: C₄₃H₄₆O₈
• Molecular Weight: 690.833
• Mol file: 82300-67-2.mol

Synonyms:1-deoxy-1-(C-2',4',6'-trimethoxyphenyl) 2,3,4,6-tetra-O-benzyl-β-D-glucopyranoside

Chemical Property of 1-deoxy-1-(C-2',4',6'-trimethoxyphenyl) 2,3,4,6-tetra-O-benzyl-β-D-glucopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-deoxy-1-(C-2',4',6'-trimethoxyphenyl) 2,3,4,6-tetra-O-benzyl-β-D-glucopyranoside

There total 22 articles about 1-deoxy-1-(C-2',4',6'-trimethoxyphenyl) 2,3,4,6-tetra-O-benzyl-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

1,2,3-trimethoxybenzene (621-23-8) + 2,3,4,6-tetra-O-benzyl-1-O-(trifluoroacetyl)-α-D-glucopyranose (125343-69-3) → 1-deoxy-1-(C-2',4',6'-trimethoxyphenyl) 2,3,4,6-tetra-O-benzyl-β-D-glucopyranoside (82300-67-2)

Guidance literature:

With boron trifluoride diethyl etherate; In dichloromethane; for 0.0833333h; Ambient temperature;

DOI:10.1016/0008-6215(89)85052-9

Reference yield: 87.0%

1,2,3-trimethoxybenzene (621-23-8) + 1-α-O-(3,5-dinitro-benzoyl)-2,3,4,6-tetra-O-benzyl-D-glucopyranose (124647-05-8) → 1-deoxy-1-(C-2',4',6'-trimethoxyphenyl) 2,3,4,6-tetra-O-benzyl-β-D-glucopyranoside (82300-67-2)

Guidance literature:

With boron trifluoride diethyl etherate; In dichloromethane; for 0.0833333h; Ambient temperature;

Reference yield: 84.0%

1,2,3-trimethoxybenzene (621-23-8) + 2,3,4,6-tetra-O-benzyl-D-glucopyranosyl fluoride (78153-79-4,89025-46-7,94898-42-7,94898-43-8,101966-50-1,143615-35-4,122741-44-0) → 1-deoxy-1-(C-2',4',6'-trimethoxyphenyl) 2,3,4,6-tetra-O-benzyl-β-D-glucopyranoside (82300-67-2)

Guidance literature:

With Cp₂Zr(H₂O)₃(OSO₂C₈F₁₇)₂·THF; In dichloromethane; at 20 ℃; for 4h; Molecular sieve;

DOI:10.1016/j.jorganchem.2008.12.057

upstream raw materials:

1-chloro-2,3,4,6-tetra-O-benzyl-D-glucopyranoside

1,2,3-trimethoxybenzene

2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl 4-nitrobenzoate

2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl trichloroacetimidate

Downstream raw materials:

β-D-glucopyranosyl-2,4,6-trimethoxybenzene

2,4,6-Trimethoxy-2-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)benzene

1,6,7-trihydroxy-3-methoxylxanthone-2-C-β-D-glucopyranoside