PHENYL VINYLSULFONATE

Base Information

• Chemical Name: PHENYL VINYLSULFONATE
• CAS No.: 1562-34-1
• Molecular Formula: C8H8O3S
• Molecular Weight: 184.216
• Hs Code.: 2906299090
• Mol file: 1562-34-1.mol

Synonyms:Ethylenesulfonicacid, phenyl ester;Phenyl ethenesulfonate;Phenyl ethylenesulfonate;Phenylvinylsulfonate;

Chemical Property of PHENYL VINYLSULFONATE

Chemical Property:

• Vapor Pressure: 0.559mmHg at 25°C
• Melting Point: 38-42 °C(lit.)
• Refractive Index: 1.547
• Boiling Point: 44-46 °C2 mm Hg(lit.)
• Flash Point: 72.6°C
• PSA: 51.75000
• Density: 1.261g/cm³
• LogP: 2.61950
• Storage Temp.: Amber Vial, -20°C Freezer, Under inert atmosphere
• Solubility.: Chloroform (Slightly), DMSO (Slightly)

Purity/Quality:

98%,99%, ^*data from raw suppliers

PhenylEthenesulfonate ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-37/39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Technology Process of PHENYL VINYLSULFONATE

There total 4 articles about PHENYL VINYLSULFONATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

2-Chloroethanesulfonyl chloride (1622-32-8) + phenol (108-95-2,27073-41-2) → phenyl vinylsulfonate (1562-34-1)

Guidance literature:

With triethylamine; In dichloromethane; at 0 ℃; for 12h; Inert atmosphere;

DOI:10.1021/acs.jmedchem.5b00099

Reference yield:

phenol (108-95-2,27073-41-2) → phenyl vinylsulfonate (1562-34-1)

Guidance literature:

Reference yield:

vinylsulfonyl chloride (6608-47-5) + sodium phenoxide (139-02-6) → phenyl vinylsulfonate (1562-34-1)

Guidance literature:

With 1,4-dioxane; at 10 ℃;

upstream raw materials:

vinylsulfonyl chloride

sodium phenoxide

2-Chloroethanesulfonyl chloride

phenol

Downstream raw materials:

β-tert-Butylperoxyaethylsulfonsaeurephenylester

β-Cumylperoxy-ethylsulfonsaeurephenylester

2-(1,1-Dimethyl-2-phenyl-ethylperoxy)-ethanesulfonic acid phenyl ester

2-(1,1-Dimethyl-2-o-tolyl-ethylperoxy)-ethanesulfonic acid phenyl ester

Refernces

• 1、 Blackburn, Bryan G.,Cooke, Maria Victoria,Laulhé, Sébastien,Niu, Ben,Sachidanandan, Krishnakumar. "Metal-free visible-light-promoted C(sp3)-H functionalization of aliphatic cyclic ethers using trace O2". supporting information. p. 9454 - 9459. Retrieved 2021/12/09.
• 2、 Solé, Daniel,Pérez-Janer, Ferran,García-Rodeja, Yago,Fernández, Israel. "Exploring Partners for the Domino α-Arylation/Michael Addition Reaction Leading to Tetrahydroisoquinolines". supporting information. p. 799 - 805. Retrieved 2017/02/15.