Naphthalene, 1-[(ethenyloxy)methyl]-

Base Information

Chemical Name:Naphthalene, 1-[(ethenyloxy)methyl]-
CAS No.:48140-70-1
Molecular Formula:C13H12O
Molecular Weight:
Hs Code.:
DSSTox Substance ID:DTXSID80451233
Nikkaji Number:J801.442F
Wikidata:Q82271154

Synonyms:48140-70-1;Naphthalene, 1-[(ethenyloxy)methyl]-;(1-Naphthylmethyl)vinyl ether;SCHEMBL14803712;DTXSID80451233

Suppliers and Price of Naphthalene, 1-[(ethenyloxy)methyl]-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Naphthalene, 1-[(ethenyloxy)methyl]-

Chemical Property:

XLogP3:3.7
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:3
Exact Mass:184.088815002
Heavy Atom Count:14
Complexity:188

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C=COCC1=CC=CC2=CC=CC=C21

Technology Process of Naphthalene, 1-[(ethenyloxy)methyl]-

There total 1 articles about Naphthalene, 1-[(ethenyloxy)methyl]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1-bromo-2.3-epoxy-3-(1-naphthyl)propane

: 2489-86-3
1-allylnaphthalene

: 48140-70-1
1-naphthylmethyl vinyl ether

: 22767-77-7,53269-01-5,53269-00-4
(Z)-1-(1-naphthyl)-propene

: 22767-77-7
1-[(1E)-prop-1-en-1-yl]naphthalene

Guidance literature:: With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; phosphorous acid trimethyl ester; In benzene; Heating;
DOI:10.1021/ja020761x

Reference yield:

: 48140-70-1
1-naphthylmethyl vinyl ether

: 162273-02-1
(4R,6S)-4-Hydroxy-6-(naphthalen-1-ylmethoxy)-cyclohex-1-enecarboxylic acid methyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) (R)-(+)-1,1'-bi-2-naphthol-TiCl₂(OPr-i)2 / 1) toluene, 50 deg C, 4 h; 2) toluene, -30 deg C, 12 h

2: 1.) lithium allyloxide, 2.) formic acid, Et₃N, palladium(II) acetate, triphenylphosphine, 3.) DBU

With formic acid; (R)-(+)-1,1'-bi-2-naphthol titanium dichloride diisopropoxide; lithium allyl oxide; palladium diacetate; 1,8-diazabicyclo[5.4.0]undec-7-ene; triethylamine; triphenylphosphine;
DOI:10.1021/jo9515900

Reference yield:

: 48140-70-1
1-naphthylmethyl vinyl ether

: 173914-18-6
(1S,4S,6S)-4-Hydroxy-6-(naphthalen-1-ylmethoxy)-cyclohex-2-ene-1,1-dicarboxylic acid allyl ester methyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 86 percent / (R)-(+)-1,1'-bi-2-naphthol titanium dichloride diisopropoxide complex / toluene / 12 h / -30 °C

2: 98 percent

With (R)-(+)-1,1'-bi-2-naphthol titanium dichloride diisopropoxide; In toluene;
DOI:10.1016/S0040-4039(00)78338-9