Methyl 3-bromocyclobutane-1-carboxylate

Base Information

Chemical Name:Methyl 3-bromocyclobutane-1-carboxylate
CAS No.:4935-00-6
Molecular Formula:C6H9BrO2
Molecular Weight:193.04
Hs Code.:2916200090
European Community (EC) Number:837-273-8,837-274-3
DSSTox Substance ID:DTXSID80785181,DTXSID201192971,DTXSID601200815
Mol file:4935-00-6.mol

Synonyms:methyl 3-bromocyclobutane-1-carboxylate;4935-00-6;1523618-35-0;methyl trans-3-bromocyclobutane-1-carboxylate;1638771-96-6;trans-Methyl 3-bromocyclobutanecarboxylate;Methyl cis-3-bromocyclobutane-1-carboxylate;Methyl 3-bromocyclobutanecarboxylate;methylcis-3-bromocyclobutane-1-carboxylate;Cyclobutanecarboxylic acid, 3-bromo-, methyl ester;methyl (1r,3r)-3-bromocyclobutane-1-carboxylate;3-Brom-cyclobutan-carbonsaeure-methylester;SCHEMBL20945853;DTXSID80785181;DTXSID201192971;DTXSID601200815;AMY34213;YKC61835;MFCD20625735;MFCD27987093;AKOS025290993;AM85789;SB12039;SB12059;SB12060;AS-34051;AS-34054;CS-0048877;CS-0049107;CS-0055633;EN300-251358;EN300-252502;P14334;EN300-1721265;methyl (1s,3s)-3-bromocyclobutane-1-carboxylate;A883908;Cyclobutanecarboxylic acid, 3-bromo-, methyl ester, cis-;Cyclobutanecarboxylic acid, 3-bromo-, methyl ester, trans-;Methyl trans-3-bromocyclobutane-1-carboxylate, AldrichCPR

Suppliers and Price of Methyl 3-bromocyclobutane-1-carboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
Methyl3-Bromocyclobutane-1-carboxylate
50mg
$ 60.00

TRC
Methyl3-Bromocyclobutane-1-carboxylate
10mg
$ 45.00

SynQuest Laboratories
Methyl 3-bromocyclobutane-1-carboxylate 97.0%
250 mg
$ 630.00

Matrix Scientific
Methyl3-bromocyclobutane-1-carboxylate 97.0%
1g
$ 1403.00

Crysdot
Methyl3-bromocyclobutanecarboxylate 95+%
1g
$ 839.00

Chemenu
methyl3-bromocyclobutane-1-carboxylate 95+%
5g
$ 356.00

Chemenu
methyl3-bromocyclobutane-1-carboxylate 95+%
25g
$ 1069.00

Chemenu
methyl3-bromocyclobutane-1-carboxylate 95+%
10g
$ 541.00

American Custom Chemicals Corporation
METHYL-3-BROMOCYCLOBUTANE-1-CARBOXYLATE 95.00%
5MG
$ 495.62

Ambeed
Methyl3-bromocyclobutanecarboxylate 98%
5g
$ 311.00

Total 18 raw suppliers

Chemical Property of Methyl 3-bromocyclobutane-1-carboxylate

Chemical Property:

Boiling Point:193.8±33.0 °C(Predicted)
PSA：26.30000
Density:1.570±0.06 g/cm3(Predicted)
LogP:1.33290
Storage Temp.:Sealed in dry,Store in freezer, under -20°C
XLogP3:1.4
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:2
Exact Mass:191.97859
Heavy Atom Count:9
Complexity:118

Purity/Quality:

99%, ^*data from raw suppliers

Methyl3-Bromocyclobutane-1-carboxylate ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC(=O)C1CC(C1)Br

Technology Process of Methyl 3-bromocyclobutane-1-carboxylate

There total 6 articles about Methyl 3-bromocyclobutane-1-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 4934-99-0
methylester of 3-hydroxycyclobutane-1-carboxylic acid

: 4935-00-6
methyl 3-bromocyclobutanecarboxylate

Guidance literature:: Multistep reaction; (i) PhSO₂Cl, Py, (ii) LiBr, acetone;
DOI:10.1016/S0040-4020(01)98361-9

Reference yield:

: 4934-98-9
methylester of 3-benzyloxycyclobutane-1-carboxylic acid

: 4935-00-6
methyl 3-bromocyclobutanecarboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: H₂ / Pd / methanol

2: (i) PhSO₂Cl, Py, (ii) LiBr, acetone

With hydrogen; palladium; In methanol;
DOI:10.1016/S0040-4020(01)98361-9

Reference yield:

: 4934-97-8
diisoamyl 3-benzyloxycyclobutane-1,1-dicarboxylate

: 4935-00-6
methyl 3-bromocyclobutanecarboxylate

Guidance literature:: Multi-step reaction with 4 steps

1: (i) KOH, aq. EtOH, (ii) (decarboxylation)

2: H₂SO₄ / 1,2-dichloro-ethane

3: H₂ / Pd / methanol

4: (i) PhSO₂Cl, Py, (ii) LiBr, acetone

With sulfuric acid; hydrogen; palladium; In methanol; 1,2-dichloro-ethane;
DOI:10.1016/S0040-4020(01)98361-9