Technology Process of Benzene, [[(8-bromo-3,7-dimethyl-6-octenyl)oxy]methyl]-
There total 5 articles about Benzene, [[(8-bromo-3,7-dimethyl-6-octenyl)oxy]methyl]- which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
8-benzyloxy-2,6-dimethyl-oct-2-en-1-ol;
With
methanesulfonyl chloride; triethylamine;
In
dichloromethane;
at -50 ℃;
for 1h;
With
lithium bromide;
In
tetrahydrofuran; dichloromethane;
at -20 ℃;
for 2h;
Further stages.;
DOI:10.1039/b206451k
- Guidance literature:
-
Multi-step reaction with 4 steps
1.1: NaH / tetrahydrofuran; hexane / 2 h / Heating
1.2: 58 percent / tetrabutylammonium iodide / tetrahydrofuran; hexane / 18 h / Heating
2.1: 12 percent / SeO2; t-BuOOH / CH2Cl2; H2O / 16 h
3.1: 33 percent / NaBH4 / ethanol; CH2Cl2; H2O / 16 h
4.1: Et3N; MeSO2Cl / CH2Cl2 / 1 h / -50 °C
4.2: 71 percent / LiBr / tetrahydrofuran; CH2Cl2 / 2 h / -20 °C
With
tert.-butylhydroperoxide; sodium tetrahydroborate; selenium(IV) oxide; sodium hydride; methanesulfonyl chloride; triethylamine;
In
tetrahydrofuran; ethanol; hexane; dichloromethane; water;
DOI:10.1039/b206451k
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: 12 percent / SeO2; t-BuOOH / CH2Cl2; H2O / 16 h
2.1: 33 percent / NaBH4 / ethanol; CH2Cl2; H2O / 16 h
3.1: Et3N; MeSO2Cl / CH2Cl2 / 1 h / -50 °C
3.2: 71 percent / LiBr / tetrahydrofuran; CH2Cl2 / 2 h / -20 °C
With
tert.-butylhydroperoxide; sodium tetrahydroborate; selenium(IV) oxide; methanesulfonyl chloride; triethylamine;
In
ethanol; dichloromethane; water;
DOI:10.1039/b206451k
